Palladacycle-Catalyzed Methylenecyclopropanation of Bicyclic Alkenes with Propiolates
2013-11-15T00:00:00Z (GMT) by
An efficient way to access functionalized methylenecyclopropanes has been developed by palladacycle-catalyzed cyclopropanation of bicyclic alkenes with propiolates in high yields. The structure of the palladacycle was kept intact in the reaction, shown by <sup>31</sup>P NMR spectrum studies. A rational mechanism has been proposed with a deuterium-labeled experiment. The usefulness of the functionalized methylenecyclopropanes has also been demonstrated.