ic900107p_si_002.cif (24.26 kB)

New Crystalline Layered Zinc Phosphate with 10-Membered-Ring Channels Perpendicular to Layers

dataset

posted on 2009-06-01, 00:00 authored by Lei Liu, Stanislav Ferdov, Cristina Coelho, Ying Kong, Luís Mafra, Jin P. Li, Jin X. Dong, Uwe Kolitsch, Rute A. Sá Ferreira, Ekkehart Tillmanns, João Rocha, Zhi Lin

A novel layered zinc phosphate, [N₂C₆H₁₂]₂[Zn₇H₃(HPO_4−x)₅(PO₄)₃]H₂O, with unique 10-membered-ring ellipsoidal channels running perpendicularly to ladder-shaped tetrahedral layers, has been synthesized ionothermally via in situ generation of 1,4-diazabicyclo[2.2.2]octane.