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Modeling Ozone Removal to Indoor Materials, Including the Effects of Porosity, Pore Diameter, and Thickness
journal contribution
posted on 2015-04-07, 00:00 authored by Elliott
T. Gall, Jeffrey A. Siegel, Richard L. CorsiWe develop an ozone
transport and reaction model to determine reaction
probabilities and assess the importance of physical properties such
as porosity, pore diameter, and material thickness on reactive uptake
of ozone to five materials. The one-dimensional model accounts for
molecular diffusion from bulk air to the air–material interface,
reaction at the interface, and diffusive transport and reaction through
material pore volumes. Material-ozone reaction probabilities that
account for internal transport and internal pore area, γipa, are determined by a minimization of residuals between
predicted and experimentally derived ozone concentrations. Values
of γipa are generally less than effective reaction
probabilities (γeff) determined previously, likely
because of the inclusion of diffusion into substrates and reaction
with internal surface area (rather than the use of the horizontally
projected external material areas). Estimates of γipa average 1 × 10–7, 2 × 10–7, 4 × 10–5, 2 × 10–5, and 4 × 10–7 for two types of cellulose
paper, pervious pavement, Portland cement concrete, and an activated
carbon cloth, respectively. The transport and reaction model developed
here accounts for observed differences in ozone removal to varying
thicknesses of the cellulose paper, and estimates a near constant
γipa as material thickness increases from 0.02 to
0.16 cm.