jo8b03048_si_001.cif (934.35 kB)
Metal-Free Regioselective Cross Dehydrogenative Coupling of Cyclic Ethers and Aryl Carbonyls
dataset
posted on 2019-01-15, 00:00 authored by Kishor
D. Mane, Anagh Mukherjee, Kumar Vanka, Gurunath SuryavanshiA highly regioselective,
efficient, and metal-free oxidative cross
dehydrogenative coupling (CDC) of aryl carbonyls with cyclic ethers
has been developed. This method offers easy access to substituted
α-arylated cyclic ethers with a high functional group tolerance
in good to excellent yields. The regioselectivity of this CDC reaction
was confirmed by density functional theory (DFT)-based calculations.