ja413008a_si_001.cif (109.18 kB)
Intermolecular/Intramolecular Sequential Aldol Reaction
dataset
posted on 2014-01-29, 00:00 authored by Atsuto Izumiseki, Hisashi YamamotoThe first example of intermolecular/intramolecular
sequential aldol
reaction of disilyl enol ethers is described. This strategy enables
the formation of five-, six-, and seven-membered ring products. Four
or more contiguous stereogenic centers are created with high levels
of relative stereochemical control.