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Improved Ethanol Adsorption Capacity and Coefficient of Performance for Adsorption Chillers of Cu-BTC@GO Composite Prepared by Rapid Room Temperature Synthesis
journal contribution
posted on 2016-10-27, 00:00 authored by Jian Yan, Ying Yu, Jing Xiao, Yingwei Li, Zhong LiA composite of Cu-BTC and graphite
oxide (GO) was prepared by rapid
room-temperature synthesis method for thermally driven adsorption
chillers (TDCs). A series of composites Cu-BTC@GO with varied GO loading
were synthesized at room temperature within 1 min, and characterized
by N2 adsorption test, scanning electron microscopy, powder
X-ray diffraction, and Fourier transform infrared analysis. The adsorption
isotherms of ethanol on the composites were measured at different
temperatures, and then, the isosteric heats of ethanol adsorption
were estimated. The composite working capacities and coefficient of
performance (COP) of the composite–ethanol working pair were
calculated for the application of refrigeration. Results showed that
Cu-BTC@GO possessed a superhigh adsorption capacity for ethanol up
to 13.60 mmol/g at 303 K, which was attributed to introduction of
GO leading to increases in the surface dispersive forces and the mesoporous
volume of Cu-BTC@GO. The isosteric heat of ethanol adsorption on Cu-BTC@GO
was slightly higher than that of Cu-BTC. The adsorption capacity of
Cu-BTC@GO was higher than many other metal–organic frameworks
(MOFs) under the application conditions of TDCs. The composites exhibited
5.8–17.4% higher working capacity and energy efficiency than
parent Cu-BTC for the application of refrigeration. The rapid room-temperature
synthesis approach has potential for the preparation of new MOF-based
composites.