High Uptakes of CO<sub>2</sub> and CH<sub>4</sub> in Mesoporous MetalOrganic Frameworks MIL-100 and MIL-101
2008-07-15T00:00:00Z (GMT) by
Mesoporous MOFs MIL-100 and MIL-101 adsorb huge amounts of CO<sub>2</sub> and CH<sub>4</sub>. Characterization was performed using both manometry and gravimetry in different laboratories for isotherms coupled with microcalorimetry and FTIR to specify the gassolid interactions. In particular, the uptake of carbon dioxide in MIL-101 has been shown to occur with a record capacity of 40 mmol g<sup>−1</sup> or 390 cm<sup>3</sup><sub>STP</sub> cm<sup>−3</sup> at 5 MPa and 303 K.