jo6b02244_si_001.pdf (1.21 MB)
General Method for the Synthesis of Functionalized Tetrabenzo[8]circulenes
journal contribution
posted on 2016-11-04, 00:00 authored by Robert
W. Miller, Summer E. Averill, Stephen J. Van Wyck, Adam C. WhalleyFunctionalized derivatives of the
saddle-shaped molecule tetrabenzo[8]circulene
were successfully synthesized through a Diels–Alder/oxidative
cyclodehydrogenation approach. This methodology improves on our previously
reported synthesis, affording products containing both electron-rich
and electron-poor functional groups from readily available starting
materials in a more efficient manner. The optoelectronic effects that
result from the introduction of this functionality are presented and
briefly discussed.