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Deprotonation of Organic Compounds Bearing Acid Protons Promoted by Metal Amido Complexes with Chiral Diamine Ligands Leading to New Organometallic Compounds
journal contribution
posted on 2002-01-14, 00:00 authored by Kunihiko Murata, Hirokazu Konishi, Masato Ito, Takao IkariyaWell-defined 16-electron metal amido complexes bearing chiral Ts-diamine ligands readily react
with nitromethane, acetone, or phenylacetylene to give
new organometallic compounds in almost quantitative
yields. For example, an Ir amido complex, Cp*Ir[(R,R)-Tscydn], reacts with nitromethane at room temperature
to give quantitatively a nitromethyl Ir complex, Cp*Ir(CH2NO2)[(R,R)-Tscydn], as a single diastereomer. The
isolable organometallic compounds with chiral amine
ligands are relevant to active catalysts for asymmetric
C−C bond formation.
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OrganometallicNewIr amidoisolable organometallic compoundsDeprotonationnitromethyl Irchiral amine ligandscomplexnitromethaneProtons PromotedChiral Diamine LigandsformationTscydnbondphenylacetylenediastereomerelectronMetal Amido Complexesorganometallic compoundsacetoneOrganic Compounds Bearingyieldroom temperatureCpcatalyst
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