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Debonding on Demand with Highly Cross-Linked Photopolymers: A Combination of Network Regulation and Thermally Induced Gas Formation
journal contribution
posted on 2018-01-16, 20:00 authored by Christian Gorsche, Christoph Schnoell, Thomas Koch, Norbert Moszner, Robert LiskaPhotopolymerizable
glues and cements that offer debonding on demand (DoD) through an
external stimulus are of great interest for the fields of recycling
and repair. State-of-the-art DoD solutions often require a high-energy
impulse (e.g., >200 °C, strong force), which is due to the
typical glassy nature of such photopolymer networks. Herein, various
blocked isocyanates (BICs) that enable thermally induced gas formation
at temperatures far below 200 °C are studied. Thermally induced
gas bubble formation is accomplished within a linear, thermoplastic
poly(N-acryloylmorpholine) matrix above glass
transition temperature, introducing porosity. The resulting porosity
within the material then causes mechanical failure. However, highly
cross-linked photopolymer networks remain unchanged due to their glassy
nature at temperatures well above 150 °C. A BIC-based thermolabile photopolymerizable
cross-linker is prepared in order to create a polymer network with
cleavable cross-link. Additionally, a β-allyl sulfone-based
chain transfer reagent is used to tune the final cross-linking density
and thermomechanical properties of the material. Above the resulting
sharp glass transition (>60 °C), plastic deformation becomes
possible, thus allowing formation of porosity. This introduces a covalently
cross-linked, thermolabile photopolymer with a tailored network architecture
as potential glue for DoD at ∼150 °C.
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covalently cross-linkedthermolabile photopolymergas bubble formationmaterialNetwork RegulationState-of-the-art DoD solutionsBIC-based thermolabile photopolymerizable cross-linkernaturepolymer networkphotopolymer networksglass transition temperatureThermally Induced Gas Formation Photopolymerizable gluesgas formationcross-linking densityCross-Linked Photopolymersthermomechanical propertiescleavable cross-linkcross-linked photopolymer networksβ- allyl sulfone-based chain transfer reagentnetwork architectureporosityoffer debonding
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