Data_Sheet_2_Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes.ZIP (1.79 MB)
Data_Sheet_2_Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes.ZIP
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posted on 2018-06-21, 04:21 authored by Akina Yoshizawa, Antonio Feula, Andrew G. Leach, Louise Male, John S. FosseySeven N,N'-palladium(II) chloride complexes, one N,N'-palladium(II) acetate complex of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride N,N'-complexes of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A CNN' metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4-cis-disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.
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