ac5b01774_si_001.pdf (1.28 MB)
Anion Recognition Triggered Nanoribbon-Like Self-Assembly: A Fluorescent Chemosensor for Nitrate in Acidic Aqueous Solution and Living Cells
journal contribution
posted on 2015-07-21, 00:00 authored by Yaping Yang, Shiyan Chen, Xin-Long NiA water-soluble
π-conjugated bispyridinium phenylenevinylene-based
fluorogenic probe has been developed as a novel fluorescent chemosensor
for highly selective, sensitive, and rapid detection of NO3– anion in acidic aqueous media. This system self-assembles
to a nanoribbon as a result of ionic interaction. The positively charged
chemosensor generates a nearly instantaneous significant fluorescence
signal (475 vs 605 nm) in response to NO3– in the green/yellow spectral region, with a large Stokes shift (130
nm). The fluorescence changes can be attributed to the self-aggregation
of the sensor triggered by ionic interaction, which occurs as a consequence
of the subtle cooperation of electrostatic ionic bonding, van der
Waals forces, and π-stacking of the π-conjugated aromatic
moieties. Importantly, this chemosensor has been employed for the
first time for the fluorescence detection of intracellular NO3– anion in cultured cells.