Infrared spectroscopic investigation of two isomers of the weakly bound complex OCS-(CO2)2 by J. Norooz Oliaee, F. Mivehvar, M. Dehghany, and N. Moazzen-Ahmadi Table A-5. Observed transitions in the band of isomer II of 18OCS - (13C16O2)2 in the OCS nu1 fundamental region and the lower state combination differences (values in units of 1/cm). ***************************************************************************************** J' Ka' Kc' J" Ka" Kc" Observed Calculated Obs-Calc Weight ***************************************************************************************** 12 1 12 13 1 13 2014.91066 2014.91087 -0.00020 0.2 12 0 12 13 0 13 2014.91066 2014.91087 -0.00020 0.2 11 1 11 12 1 12 2014.94985 2014.94998 -0.00013 0.2 11 0 11 12 0 12 2014.94985 2014.94998 -0.00012 0.2 10 1 10 11 1 11 2014.98865 2014.98909 -0.00043 1.0 10 0 10 11 0 11 2014.98865 2014.98907 -0.00041 1.0 8 0 8 9 0 9 2015.06780 2015.06723 0.00056 1.0 8 1 8 9 1 9 2015.06780 2015.06735 0.00044 1.0 7 0 7 8 0 8 2015.10654 2015.10629 0.00024 0.2 7 1 7 8 1 8 2015.10654 2015.10657 -0.00003 0.2 6 2 5 7 2 6 2015.12200 2015.12150 0.00050 1.0 5 2 3 6 2 4 2015.13730 2015.13704 0.00025 1.0 6 1 6 7 1 7 2015.14592 2015.14592 -0.00000 0.2 6 0 6 7 0 7 2015.14592 2015.14529 0.00063 0.2 5 1 4 6 1 5 2015.15332 2015.15253 0.00078 0.2 5 2 4 6 2 5 2015.16396 2015.16351 0.00045 1.0 5 0 5 6 0 6 2015.18544 2015.18415 0.00129 0.1 5 1 5 6 1 6 2015.18544 2015.18552 -0.00007 0.1 4 1 3 5 1 4 2015.19476 2015.19441 0.00035 0.2 4 2 3 5 2 4 2015.20666 2015.20665 0.00001 1.0 4 0 4 5 0 5 2015.22278 2015.22283 -0.00005 1.0 4 1 4 5 1 5 2015.22518 2015.22551 -0.00033 1.0 3 1 2 4 1 3 2015.23899 2015.23934 -0.00035 0.2 3 2 1 4 2 2 2015.23899 2015.23896 0.00002 0.2 3 2 2 4 2 3 2015.25070 2015.25094 -0.00023 1.0 3 1 3 4 1 4 2015.26611 2015.26610 0.00001 1.0 2 2 0 3 2 1 2015.29048 2015.29071 -0.00023 1.0 2 2 1 3 2 2 2015.29602 2015.29624 -0.00022 1.0 2 0 2 3 0 3 2015.30161 2015.30164 -0.00003 1.0 2 1 2 3 1 3 2015.30738 2015.30746 -0.00007 1.0 1 1 0 2 1 1 2015.33554 2015.33572 -0.00017 1.0 1 0 1 2 0 2 2015.34405 2015.34414 -0.00008 1.0 1 1 1 2 1 2 2015.34969 2015.34966 0.00003 1.0 5 2 3 5 2 4 2015.47536 2015.47535 0.00000 0.2 1 0 1 0 0 0 2015.48275 2015.48274 0.00001 1.0 2 1 2 1 1 1 2015.52284 2015.52267 0.00017 1.0 2 0 2 1 0 1 2015.52823 2015.52811 0.00011 1.0 3 1 3 2 1 2 2015.56510 2015.56528 -0.00018 1.0 3 0 3 2 0 2 2015.57101 2015.57101 0.00000 1.0 3 2 2 2 2 1 2015.57666 2015.57662 0.00003 1.0 3 2 1 2 2 0 2015.58228 2015.58211 0.00016 1.0 3 1 2 2 1 1 2015.58595 2015.58590 0.00005 1.0 4 2 3 3 2 2 2015.62257 2015.62245 0.00012 1.0 4 2 2 3 2 1 2015.63404 2015.63432 -0.00027 0.2 4 1 3 3 1 2 2015.63404 2015.63379 0.00025 0.2 5 1 5 4 1 4 2015.64836 2015.64852 -0.00016 1.0 5 0 5 4 0 4 2015.65112 2015.65115 -0.00003 1.0 5 2 4 4 2 3 2015.66735 2015.66740 -0.00005 1.0 5 2 3 4 2 2 2015.68704 2015.68660 0.00043 0.1 6 2 5 5 2 4 2015.71168 2015.71135 0.00032 1.0 7 0 7 6 0 6 2015.72997 2015.73059 -0.00062 0.2 7 1 7 6 1 6 2015.72997 2015.72997 -0.00000 0.2 6 2 4 5 2 3 2015.73747 2015.73749 -0.00002 1.0 7 3 5 6 3 4 2015.76794 2015.76851 -0.00056 1.0 8 0 8 7 0 7 2015.77079 2015.77070 0.00009 0.2 8 1 8 7 1 7 2015.77079 2015.77043 0.00036 0.2 7 4 3 6 4 2 2015.77423 2015.77405 0.00018 1.0 9 1 9 8 1 8 2015.81024 2015.81083 -0.00058 0.2 9 0 9 8 0 8 2015.81024 2015.81094 -0.00069 0.2 8 2 6 7 2 5 2015.83162 2015.83173 -0.00011 1.0 8 2 6 7 2 5 2015.83166 2015.83173 -0.00006 1.0 10 0 10 9 0 9 2015.85094 2015.85125 -0.00031 0.2 10 1 10 9 1 9 2015.85094 2015.85120 -0.00026 0.2 9 3 7 8 3 6 2015.85889 2015.85899 -0.00010 1.0 11 1 11 10 1 10 2015.89117 2015.89157 -0.00039 0.2 11 0 11 10 0 10 2015.89117 2015.89158 -0.00041 0.2 14 0 14 13 0 13 2016.01256 2016.01247 0.00009 1.0 14 1 14 13 1 13 2016.01256 2016.01247 0.00009 1.0 Combination differences ***************************************************************************************** J' Ka' Kc' J" Ka" Kc" Observed Calculated Obs-Calc Weight ***************************************************************************************** 2 0 2 0 0 0 0.13868 0.13860 0.00008 1.0 3 0 3 1 0 1 0.22661 0.22646 0.00015 1.0 3 1 3 1 1 1 0.21542 0.21521 0.00020 1.0 4 1 3 2 1 1 0.34696 0.34655 0.00040 1.0 4 1 4 2 1 2 0.29899 0.29918 -0.00018 1.0 4 2 2 2 2 0 0.34330 0.34314 0.00015 1.0 4 2 3 2 2 1 0.32585 0.32568 0.00016 1.0 5 1 4 3 1 2 0.43931 0.43938 -0.00006 1.0 5 2 3 3 2 1 0.44661 0.44707 -0.00045 1.0 5 2 4 3 2 2 0.41591 0.41580 0.00011 1.0 5 3 2 3 3 0 0.43086 0.43100 -0.00014 1.0 5 3 3 3 3 1 0.42428 0.42601 -0.00173 0.001 6 0 6 4 0 4 0.46567 0.46700 -0.00132 0.001 6 1 5 4 1 3 0.52588 0.52685 -0.00097 0.001 6 1 6 4 1 4 0.46300 0.46300 -0.00000 1.0 6 2 4 4 2 2 0.54965 0.54956 0.00008 1.0 6 2 5 4 2 3 0.50346 0.50389 -0.00043 1.0 6 3 3 4 3 1 0.53342 0.53348 -0.00005 0.25 7 0 7 5 0 5 0.54474 0.54544 -0.00070 0.25 7 1 7 5 1 5 0.54297 0.54345 -0.00048 0.25 7 2 5 5 2 3 0.64804 0.64823 -0.00019 1.0 7 2 6 5 2 4 0.58968 0.58985 -0.00016 1.0 7 3 4 5 3 2 0.63914 0.63937 -0.00023 0.25 8 0 8 6 0 6 0.62341 0.62430 -0.00089 0.001 8 1 8 6 1 6 0.62341 0.62340 0.00000 0.50 8 3 6 6 3 4 0.70593 0.70600 -0.00007 1.0 9 0 9 7 0 7 0.70299 0.70346 -0.00046 0.50 9 1 9 7 1 7 0.70299 0.70308 -0.00008 0.50 9 3 7 7 3 5 0.79577 0.79545 0.00031 1.0 10 0 10 8 0 8 0.78292 0.78278 0.00013 0.50 10 1 10 8 1 8 0.78292 0.78262 0.00029 0.50 10 3 8 8 3 6 0.88288 0.88248 0.00040 1.0 11 0 11 9 0 9 0.86246 0.86218 0.00028 0.50 11 1 11 9 1 9 0.86246 0.86211 0.00035 0.50 12 0 12 10 0 10 0.94128 0.94160 -0.00032 0.50 12 1 12 10 1 10 0.94128 0.94158 -0.00029 0.50 7 4 3 5 4 1 0.62145 0.62145 0.00000 0.25 7 4 4 5 4 2 0.61822 0.61827 -0.00004 0.25 7 5 2 5 5 0 0.61689 0.61622 0.00066 0.001 7 5 3 5 5 1 0.61689 0.61608 0.00081 0.001 9 1 8 7 1 6 0.76410 0.76388 0.00021 0.001 9 2 7 7 2 5 0.82834 0.82840 -0.00006 1.0 9 2 8 7 2 6 0.75718 0.75605 0.00112 0.001 9 3 6 7 3 4 0.85117 0.85113 0.00004 0.25 9 4 5 7 4 3 0.82888 0.82883 0.00004 1.0 9 4 6 7 4 4 0.81108 0.81096 0.00011 0.25 9 5 5 7 5 3 0.81103 0.81041 0.00062 0.01 10 1 9 8 1 7 0.84084 0.84126 -0.00042 0.10 10 3 7 8 3 5 0.95135 0.95106 0.00028 0.25 10 4 6 8 4 4 0.93694 0.93765 -0.00070 0.10 11 2 9 9 2 7 0.98588 0.98596 -0.00007 1.0 11 3 8 9 3 6 1.04430 1.04452 -0.00022 0.25 11 3 9 9 3 7 0.96694 0.96723 -0.00029 0.25 11 4 8 9 4 6 0.99868 0.99842 0.00026 0.50 11 5 6 9 5 4 1.01749 1.01768 -0.00019 0.50 12 2 10 10 2 8 1.06182 1.06158 0.00023 0.50 12 3 9 10 3 7 1.13070 1.13073 -0.00002 1.0 13 1 12 11 1 10 1.07628 1.07722 -0.00093 0.001 13 2 12 11 2 10 1.07628 1.07680 -0.00052 0.001 14 0 14 12 0 12 1.09973 1.10049 -0.00076 0.001 14 1 14 12 1 12 1.09973 1.10049 -0.00075 0.001 14 1 13 12 1 11 1.15598 1.15647 -0.00049 0.001 14 2 13 12 2 11 1.15598 1.15630 -0.00031 0.001 15 0 15 13 0 13 1.17937 1.17995 -0.00058 0.001 15 1 15 13 1 13 1.17937 1.17995 -0.00057 0.001 13 4 10 11 4 8 1.17584 1.17644 -0.00060 0.001