data_complex_2
_audit_creation_date               2020-12-25
_audit_creation_method
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6226)
;
_shelx_SHELXL_version_number       '2018/3'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety          
 'C112 H102 Ag2 N2 P6 Pt, 2(Cl O4), 6(C H2 Cl2)'
_chemical_formula_sum              'C118 H114 Ag2 Cl14 N2 O8 P6 Pt'
_chemical_formula_weight           2781.06
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'P' 'P' 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl' 'Cl' 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Ag' 'Ag' -0.8971 1.1015
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Pt' 'Pt' -1.7033 8.3905
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'triclinic'
_space_group_IT_number             2
_space_group_name_H-M_alt          'P -1'
_space_group_name_Hall             '-P 1'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, -z'

_cell_length_a                     13.9377(7)
_cell_length_b                     13.9995(8)
_cell_length_c                     16.3568(9)
_cell_angle_alpha                  72.665(2)
_cell_angle_beta                   86.298(2)
_cell_angle_gamma                  71.242(2)
_cell_volume                       2883.0(3)
_cell_formula_units_Z              1
_cell_measurement_reflns_used      9301
_cell_measurement_temperature      100
_cell_measurement_theta_max        25.34
_cell_measurement_theta_min        2.35
_shelx_estimated_absorpt_T_max     0.766
_shelx_estimated_absorpt_T_min     0.689
_exptl_absorpt_coefficient_mu      2.012
_exptl_absorpt_correction_T_max    0.7452
_exptl_absorpt_correction_T_min    0.6327
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0612 before and 0.0427 after correction.
The Ratio of minimum to maximum transmission is 0.8490.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              'metallic red'
_exptl_crystal_colour_lustre       metallic
_exptl_crystal_colour_modifier     .
_exptl_crystal_colour_primary      red
_exptl_crystal_density_diffrn      1.602
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         block
_exptl_crystal_F_000               1400
_exptl_crystal_size_max            0.2
_exptl_crystal_size_mid            0.17
_exptl_crystal_size_min            0.14
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0302
_diffrn_reflns_av_unetI/netI       0.0363
_diffrn_reflns_Laue_measured_fraction_full  0.990
_diffrn_reflns_Laue_measured_fraction_max  0.989
_diffrn_reflns_limit_h_max         16
_diffrn_reflns_limit_h_min         -16
_diffrn_reflns_limit_k_max         16
_diffrn_reflns_limit_k_min         -16
_diffrn_reflns_limit_l_max         19
_diffrn_reflns_limit_l_min         -19
_diffrn_reflns_number              26096
_diffrn_reflns_point_group_measured_fraction_full  0.990
_diffrn_reflns_point_group_measured_fraction_max  0.989
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           25.365
_diffrn_reflns_theta_min           2.634
_diffrn_ambient_temperature        99.96
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  0.990
_diffrn_measured_fraction_theta_max  0.989
_diffrn_measurement_device_type    'Bruker APEX-II CCD'
_diffrn_measurement_method         'φ and ω scans'
_diffrn_radiation_type             MoK\a
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     ?
_diffrn_source_current             1.4
_diffrn_source_power               0.07
_diffrn_source_voltage             50.0
_diffrn_standards_number           0
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  9578
_reflns_number_total               10457
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection         ?
_computing_data_reduction          'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics      'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement    'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution      'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max           1.395
_refine_diff_density_min           -1.306
_refine_diff_density_rms           0.104
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.058
_refine_ls_hydrogen_treatment      constr
_refine_ls_matrix_type             full
_refine_ls_number_parameters       686
_refine_ls_number_reflns           10457
_refine_ls_number_restraints       0
_refine_ls_R_factor_all            0.0397
_refine_ls_R_factor_gt             0.0354
_refine_ls_restrained_S_all        1.058
_refine_ls_shift/su_max            0.002
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0370P)²+7.8108P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.0863
_refine_ls_wR_factor_ref           0.0893
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C2(H2A,H2B), C1(H1A,H1B), C58(H58A,H58B), C57(H57A,H57B), C59(H59A,H59B)
2.b Aromatic/amide H refined with riding coordinates:
 C22(H22), C8(H8), C44(H44), C18(H18), C21(H21), C49(H49), C19(H19), C55(H55),
 C35(H35), C26(H26), C54(H54), C41(H41), C5(H5), C32(H32), C48(H48), C27(H27),
 C12(H12), C14(H14), C47(H47), C52(H52), C53(H53), C25(H25), C15(H15), C40(H40),
  C20(H20), C50(H50), C7(H7), C43(H43), C56(H56), C46(H46), C28(H28), C13(H13),
 C6(H6), C33(H33), C34(H34)
2.c Idealised Me refined as rotating group:
 C10(H10A,H10B,H10C), C23(H23A,H23B,H23C), C3(H3A,H3B,H3C), C30(H30A,H30B,H30C)
;
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary       ?
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Pt1 Pt 0.500000 0.500000 0.500000 0.01410(7) Uani 1 2 d S . P . .
 Ag1 Ag 0.59581(2) 0.38326(2) 0.67151(2) 0.01979(8) Uani 1 1 d . . . . .
 P2 P 0.61721(7) 0.37640(8) 0.44643(6) 0.0157(2) Uani 1 1 d . . . . .
 P1 P 0.74998(7) 0.29443(8) 0.61125(6) 0.0170(2) Uani 1 1 d . . . . .
 P3 P 0.51536(7) 0.48412(8) 0.26585(6) 0.0169(2) Uani 1 1 d . . . . .
 Cl1 Cl 0.93726(8) 0.34564(9) 0.31754(7) 0.0287(2) Uani 1 1 d . . . . .
 Cl6 Cl 0.47784(9) 0.89456(10) -0.02994(7) 0.0347(3) Uani 1 1 d . . . . .
 Cl7 Cl 0.39884(10) 0.83288(12) 0.14100(9) 0.0475(3) Uani 1 1 d . . . . .
 Cl5 Cl 0.77316(11) 0.65034(12) 0.47368(10) 0.0519(4) Uani 1 1 d . . . . .
 Cl3 Cl 0.94928(13) 0.62160(13) 0.05010(11) 0.0615(4) Uani 1 1 d . . . . .
 Cl4 Cl 0.80427(17) 0.82715(16) 0.50855(18) 0.0986(8) Uani 1 1 d . . . . .
 Cl2 Cl 1.15614(13) 0.5113(3) 0.10781(14) 0.1070(9) Uani 1 1 d . . . . .
 O3 O 1.0411(3) 0.3143(3) 0.2959(3) 0.0553(11) Uani 1 1 d . . . . .
 O1 O 0.9278(4) 0.3966(4) 0.3831(3) 0.0730(15) Uani 1 1 d . . . . .
 O2 O 0.8781(3) 0.4179(4) 0.2443(3) 0.0767(16) Uani 1 1 d . . . . .
 O4 O 0.9006(3) 0.2566(3) 0.3490(2) 0.0414(8) Uani 1 1 d . . . . .
 C29 C 0.8600(3) 0.3169(3) 0.6469(3) 0.0208(8) Uani 1 1 d . . . . .
 C17 C 0.6042(3) 0.2497(3) 0.4533(2) 0.0215(9) Uani 1 1 d . . . . .
 C22 C 0.5086(3) 0.2364(3) 0.4622(3) 0.0234(9) Uani 1 1 d . . . . .
 H22 H 0.452408 0.288463 0.475944 0.028 Uiso 1 1 calc R U . . .
 C2 C 0.6350(3) 0.4245(3) 0.3312(2) 0.0173(8) Uani 1 1 d . . . . .
 H2A H 0.679125 0.364948 0.311647 0.021 Uiso 1 1 calc R U . . .
 H2B H 0.670444 0.477749 0.321226 0.021 Uiso 1 1 calc R U . . .
 C37 C 0.5538(3) 0.6082(3) 0.4158(2) 0.0185(8) Uani 1 1 d . . . . .
 C8 C 0.6600(3) 0.5194(3) 0.1415(3) 0.0250(9) Uani 1 1 d . . . . .
 H8 H 0.709271 0.483451 0.187168 0.030 Uiso 1 1 calc R U . . .
 C9 C 0.5576(3) 0.5321(3) 0.1577(2) 0.0198(8) Uani 1 1 d . . . . .
 N1 N 0.7710(3) 0.9394(3) 0.1226(2) 0.0223(7) Uani 1 1 d . . . . .
 C1 C 0.7415(3) 0.3531(3) 0.4936(2) 0.0175(8) Uani 1 1 d . . . . .
 H1A H 0.755694 0.421022 0.479461 0.021 Uiso 1 1 calc R U . . .
 H1B H 0.794165 0.305492 0.467545 0.021 Uiso 1 1 calc R U . . .
 C36 C 0.7770(3) 0.1536(3) 0.6285(3) 0.0259(9) Uani 1 1 d . . . . .
 C44 C 0.7022(3) 0.7018(3) 0.2435(3) 0.0222(9) Uani 1 1 d . . . . .
 H44 H 0.719809 0.629774 0.245070 0.027 Uiso 1 1 calc R U . . .
 C38 C 0.5866(3) 0.6692(3) 0.3623(3) 0.0195(8) Uani 1 1 d . . . . .
 C18 C 0.6872(4) 0.1731(3) 0.4338(3) 0.0274(9) Uani 1 1 d . . . . .
 H18 H 0.752184 0.182282 0.427857 0.033 Uiso 1 1 calc R U . . .
 C42 C 0.7239(3) 0.8727(3) 0.1817(3) 0.0200(8) Uani 1 1 d . . . . .
 C39 C 0.6305(3) 0.7394(3) 0.2996(3) 0.0202(8) Uani 1 1 d . . . . .
 C45 C 0.7908(3) 1.0234(3) 0.1441(3) 0.0226(9) Uani 1 1 d . . . . .
 C51 C 0.8094(3) 0.9176(3) 0.0449(3) 0.0217(9) Uani 1 1 d . . . . .
 C24 C 0.8944(3) 0.2714(3) 0.7331(3) 0.0238(9) Uani 1 1 d . . . . .
 C21 C 0.4963(4) 0.1464(4) 0.4509(3) 0.0330(11) Uani 1 1 d . . . . .
 H21 H 0.431533 0.136601 0.456598 0.040 Uiso 1 1 calc R U . . .
 C49 C 0.7920(4) 1.2031(4) 0.1039(3) 0.0330(11) Uani 1 1 d . . . . .
 H49 H 0.778361 1.270226 0.062396 0.040 Uiso 1 1 calc R U . . .
 C19 C 0.6740(4) 0.0838(4) 0.4233(3) 0.0376(12) Uani 1 1 d . . . . .
 H19 H 0.730252 0.031011 0.410558 0.045 Uiso 1 1 calc R U . . .
 C55 C 0.9412(4) 0.9036(4) -0.0573(3) 0.0355(11) Uani 1 1 d . . . . .
 H55 H 1.006278 0.908243 -0.074867 0.043 Uiso 1 1 calc R U . . .
 C35 C 0.6942(4) 0.1162(4) 0.6613(3) 0.0353(11) Uani 1 1 d . . . . .
 H35 H 0.632250 0.163979 0.672093 0.042 Uiso 1 1 calc R U . . .
 C26 C 1.0146(4) 0.3690(4) 0.7057(3) 0.0344(11) Uani 1 1 d . . . . .
 H26 H 1.067347 0.386422 0.725801 0.041 Uiso 1 1 calc R U . . .
 C54 C 0.8844(4) 0.8778(4) -0.1083(3) 0.0394(12) Uani 1 1 d . . . . .
 H54 H 0.910222 0.863693 -0.160172 0.047 Uiso 1 1 calc R U . . .
 C41 C 0.6508(3) 0.9117(3) 0.2372(3) 0.0243(9) Uani 1 1 d . . . . .
 H41 H 0.632407 0.983881 0.235138 0.029 Uiso 1 1 calc R U . . .
 C5 C 0.5180(4) 0.6212(4) 0.0080(3) 0.0324(11) Uani 1 1 d . . . . .
 H5 H 0.469841 0.655564 -0.038568 0.039 Uiso 1 1 calc R U . . .
 C31 C 0.8679(4) 0.0839(4) 0.6126(3) 0.0360(11) Uani 1 1 d . . . . .
 C32 C 0.8761(5) -0.0241(4) 0.6313(3) 0.0426(13) Uani 1 1 d . . . . .
 H32 H 0.937682 -0.073564 0.621990 0.051 Uiso 1 1 calc R U . . .
 C48 C 0.8330(3) 1.1869(4) 0.1832(3) 0.0326(10) Uani 1 1 d . . . . .
 H48 H 0.847282 1.242588 0.196653 0.039 Uiso 1 1 calc R U . . .
 C10 C 0.2993(4) 0.4406(4) 0.3063(3) 0.0414(12) Uani 1 1 d . . . . .
 H10A H 0.284476 0.511683 0.266112 0.062 Uiso 1 1 calc R U . . .
 H10B H 0.321412 0.440523 0.362008 0.062 Uiso 1 1 calc R U . . .
 H10C H 0.238134 0.419289 0.313037 0.062 Uiso 1 1 calc R U . . .
 C27 C 0.9798(3) 0.4140(4) 0.6217(3) 0.0327(11) Uani 1 1 d . . . . .
 H27 H 1.007872 0.463422 0.583908 0.039 Uiso 1 1 calc R U . . .
 C11 C 0.3805(4) 0.3659(4) 0.2728(3) 0.0349(11) Uani 1 1 d . . . . .
 C12 C 0.3599(4) 0.2795(4) 0.2554(3) 0.0391(12) Uani 1 1 d . . . . .
 H12 H 0.294626 0.271547 0.264931 0.047 Uiso 1 1 calc R U . . .
 C23 C 0.8504(4) 0.1948(4) 0.7970(3) 0.0311(10) Uani 1 1 d . . . . .
 H23A H 0.874926 0.126061 0.785933 0.047 Uiso 1 1 calc R U . . .
 H23B H 0.776258 0.221752 0.791141 0.047 Uiso 1 1 calc R U . . .
 H23C H 0.871606 0.187143 0.855176 0.047 Uiso 1 1 calc R U . . .
 C14 C 0.5308(4) 0.2147(4) 0.2101(3) 0.0372(12) Uani 1 1 d . . . . .
 H14 H 0.580801 0.163236 0.189956 0.045 Uiso 1 1 calc R U . . .
 C47 C 0.8531(4) 1.0886(4) 0.2431(3) 0.0324(10) Uani 1 1 d . . . . .
 H47 H 0.881023 1.076996 0.298045 0.039 Uiso 1 1 calc R U . . .
 C3 C 0.3735(3) 0.5988(4) 0.1031(3) 0.0315(10) Uani 1 1 d . . . . .
 H3A H 0.361864 0.530638 0.114945 0.047 Uiso 1 1 calc R U . . .
 H3B H 0.334450 0.648056 0.051216 0.047 Uiso 1 1 calc R U . . .
 H3C H 0.351807 0.627297 0.151607 0.047 Uiso 1 1 calc R U . . .
 C52 C 0.7515(3) 0.8923(4) -0.0069(3) 0.0283(10) Uani 1 1 d . . . . .
 H52 H 0.685977 0.888527 0.010005 0.034 Uiso 1 1 calc R U . . .
 C53 C 0.7889(4) 0.8729(4) -0.0825(3) 0.0365(11) Uani 1 1 d . . . . .
 H53 H 0.748767 0.855844 -0.117398 0.044 Uiso 1 1 calc R U . . .
 C25 C 0.9723(3) 0.2984(4) 0.7605(3) 0.0320(10) Uani 1 1 d . . . . .
 H25 H 0.996852 0.267301 0.818304 0.038 Uiso 1 1 calc R U . . .
 C30 C 0.9571(4) 0.1165(4) 0.5780(3) 0.0398(12) Uani 1 1 d . . . . .
 H30A H 0.935530 0.179481 0.528414 0.060 Uiso 1 1 calc R U . . .
 H30B H 1.006681 0.059192 0.560458 0.060 Uiso 1 1 calc R U . . .
 H30C H 0.987954 0.132560 0.622351 0.060 Uiso 1 1 calc R U . . .
 C15 C 0.5526(4) 0.2972(4) 0.2250(3) 0.0326(11) Uani 1 1 d . . . . .
 H15 H 0.618561 0.303299 0.214478 0.039 Uiso 1 1 calc R U . . .
 C40 C 0.6054(3) 0.8459(3) 0.2947(3) 0.0253(9) Uani 1 1 d . . . . .
 H40 H 0.556135 0.873757 0.331657 0.030 Uiso 1 1 calc R U . . .
 C20 C 0.5794(5) 0.0708(4) 0.4312(3) 0.0397(13) Uani 1 1 d . . . . .
 H20 H 0.571029 0.009494 0.423043 0.048 Uiso 1 1 calc R U . . .
 C50 C 0.7704(3) 1.1217(3) 0.0839(3) 0.0266(9) Uani 1 1 d . . . . .
 H50 H 0.741743 1.133631 0.029190 0.032 Uiso 1 1 calc R U . . .
 C7 C 0.6904(4) 0.5590(4) 0.0590(3) 0.0306(10) Uani 1 1 d . . . . .
 H7 H 0.759932 0.551401 0.048510 0.037 Uiso 1 1 calc R U . . .
 C16 C 0.4773(3) 0.3741(3) 0.2564(3) 0.0257(9) Uani 1 1 d . . . . .
 C43 C 0.7480(3) 0.7662(3) 0.1859(3) 0.0224(9) Uani 1 1 d . . . . .
 H43 H 0.796553 0.738067 0.148653 0.027 Uiso 1 1 calc R U . . .
 C56 C 0.9052(3) 0.9227(4) 0.0189(3) 0.0281(10) Uani 1 1 d . . . . .
 H56 H 0.945779 0.939402 0.053536 0.034 Uiso 1 1 calc R U . . .
 C4 C 0.4846(3) 0.5843(3) 0.0899(3) 0.0251(9) Uani 1 1 d . . . . .
 C46 C 0.8328(3) 1.0071(4) 0.2238(3) 0.0285(10) Uani 1 1 d . . . . .
 H46 H 0.847618 0.939747 0.265166 0.034 Uiso 1 1 calc R U . . .
 C28 C 0.9038(3) 0.3874(4) 0.5921(3) 0.0282(10) Uani 1 1 d . . . . .
 H28 H 0.881329 0.417575 0.533652 0.034 Uiso 1 1 calc R U . . .
 C13 C 0.4340(4) 0.2092(4) 0.2251(3) 0.0401(12) Uani 1 1 d . . . . .
 H13 H 0.418178 0.153152 0.213785 0.048 Uiso 1 1 calc R U . . .
 C6 C 0.6187(4) 0.6093(4) -0.0073(3) 0.0348(11) Uani 1 1 d . . . . .
 H6 H 0.639013 0.635836 -0.063794 0.042 Uiso 1 1 calc R U . . .
 C33 C 0.7950(5) -0.0566(4) 0.6628(4) 0.0505(15) Uani 1 1 d . . . . .
 H33 H 0.801895 -0.129323 0.675301 0.061 Uiso 1 1 calc R U . . .
 C58 C 0.5080(4) 0.8342(4) 0.0813(3) 0.0333(11) Uani 1 1 d . . . . .
 H58A H 0.553388 0.760851 0.090455 0.040 Uiso 1 1 calc R U . . .
 H58B H 0.544672 0.873031 0.101808 0.040 Uiso 1 1 calc R U . . .
 C34 C 0.7036(5) 0.0113(4) 0.6772(4) 0.0492(14) Uani 1 1 d . . . . .
 H34 H 0.648195 -0.013822 0.697771 0.059 Uiso 1 1 calc R U . . .
 C57 C 1.0331(4) 0.5079(5) 0.1194(4) 0.0490(14) Uani 1 1 d . . . . .
 H57A H 1.013400 0.503038 0.179415 0.059 Uiso 1 1 calc R U . . .
 H57B H 1.028743 0.444564 0.106626 0.059 Uiso 1 1 calc R U . . .
 C59 C 0.8547(4) 0.6948(5) 0.5202(4) 0.0501(14) Uani 1 1 d . . . . .
 H59A H 0.866033 0.655492 0.581929 0.060 Uiso 1 1 calc R U . . .
 H59B H 0.921053 0.680619 0.492651 0.060 Uiso 1 1 calc R U . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Pt1 Ag1 2.9448(3) . ?
 Pt1 Ag1 2.9448(3) 2_666 ?
 Pt1 P2 2.3089(10) . ?
 Pt1 P2 2.3089(10) 2_666 ?
 Pt1 C37 2.027(4) 2_666 ?
 Pt1 C37 2.027(4) . ?
 Ag1 P1 2.4235(11) . ?
 Ag1 P3 2.4446(11) 2_666 ?
 Ag1 C37 2.555(4) 2_666 ?
 P2 C17 1.811(4) . ?
 P2 C2 1.833(4) . ?
 P2 C1 1.833(4) . ?
 P1 C29 1.823(4) . ?
 P1 C1 1.849(4) . ?
 P1 C36 1.821(4) . ?
 P3 C2 1.850(4) . ?
 P3 C9 1.827(4) . ?
 P3 C16 1.831(4) . ?
 Cl1 O3 1.425(4) . ?
 Cl1 O1 1.433(4) . ?
 Cl1 O2 1.417(4) . ?
 Cl1 O4 1.440(4) . ?
 Cl6 C58 1.776(5) . ?
 Cl7 C58 1.756(5) . ?
 Cl5 C59 1.763(5) . ?
 Cl3 C57 1.756(6) . ?
 Cl4 C59 1.712(6) . ?
 Cl2 C57 1.728(6) . ?
 C29 C24 1.407(6) . ?
 C29 C28 1.392(6) . ?
 C17 C22 1.396(6) . ?
 C17 C18 1.396(6) . ?
 C22 H22 0.9500 . ?
 C22 C21 1.391(6) . ?
 C2 H2A 0.9900 . ?
 C2 H2B 0.9900 . ?
 C37 C38 1.208(6) . ?
 C8 H8 0.9500 . ?
 C8 C9 1.398(6) . ?
 C8 C7 1.392(6) . ?
 C9 C4 1.409(6) . ?
 N1 C42 1.418(5) . ?
 N1 C45 1.433(5) . ?
 N1 C51 1.426(5) . ?
 C1 H1A 0.9900 . ?
 C1 H1B 0.9900 . ?
 C36 C35 1.425(7) . ?
 C36 C31 1.393(7) . ?
 C44 H44 0.9500 . ?
 C44 C39 1.396(6) . ?
 C44 C43 1.376(6) . ?
 C38 C39 1.448(5) . ?
 C18 H18 0.9500 . ?
 C18 C19 1.381(7) . ?
 C42 C41 1.407(6) . ?
 C42 C43 1.400(6) . ?
 C39 C40 1.396(6) . ?
 C45 C50 1.385(6) . ?
 C45 C46 1.388(6) . ?
 C51 C52 1.394(6) . ?
 C51 C56 1.392(6) . ?
 C24 C23 1.512(6) . ?
 C24 C25 1.397(6) . ?
 C21 H21 0.9500 . ?
 C21 C20 1.390(8) . ?
 C49 H49 0.9500 . ?
 C49 C48 1.378(7) . ?
 C49 C50 1.398(6) . ?
 C19 H19 0.9500 . ?
 C19 C20 1.380(8) . ?
 C55 H55 0.9500 . ?
 C55 C54 1.379(7) . ?
 C55 C56 1.381(7) . ?
 C35 H35 0.9500 . ?
 C35 C34 1.377(7) . ?
 C26 H26 0.9500 . ?
 C26 C27 1.375(7) . ?
 C26 C25 1.381(7) . ?
 C54 H54 0.9500 . ?
 C54 C53 1.387(7) . ?
 C41 H41 0.9500 . ?
 C41 C40 1.385(6) . ?
 C5 H5 0.9500 . ?
 C5 C4 1.393(6) . ?
 C5 C6 1.375(7) . ?
 C31 C32 1.418(7) . ?
 C31 C30 1.481(7) . ?
 C32 H32 0.9500 . ?
 C32 C33 1.367(8) . ?
 C48 H48 0.9500 . ?
 C48 C47 1.384(7) . ?
 C10 H10A 0.9800 . ?
 C10 H10B 0.9800 . ?
 C10 H10C 0.9800 . ?
 C10 C11 1.475(8) . ?
 C27 H27 0.9500 . ?
 C27 C28 1.387(6) . ?
 C11 C12 1.436(7) . ?
 C11 C16 1.393(6) . ?
 C12 H12 0.9500 . ?
 C12 C13 1.360(8) . ?
 C23 H23A 0.9800 . ?
 C23 H23B 0.9800 . ?
 C23 H23C 0.9800 . ?
 C14 H14 0.9500 . ?
 C14 C15 1.374(7) . ?
 C14 C13 1.378(7) . ?
 C47 H47 0.9500 . ?
 C47 C46 1.385(7) . ?
 C3 H3A 0.9800 . ?
 C3 H3B 0.9800 . ?
 C3 H3C 0.9800 . ?
 C3 C4 1.505(6) . ?
 C52 H52 0.9500 . ?
 C52 C53 1.380(7) . ?
 C53 H53 0.9500 . ?
 C25 H25 0.9500 . ?
 C30 H30A 0.9800 . ?
 C30 H30B 0.9800 . ?
 C30 H30C 0.9800 . ?
 C15 H15 0.9500 . ?
 C15 C16 1.435(7) . ?
 C40 H40 0.9500 . ?
 C20 H20 0.9500 . ?
 C50 H50 0.9500 . ?
 C7 H7 0.9500 . ?
 C7 C6 1.380(7) . ?
 C43 H43 0.9500 . ?
 C56 H56 0.9500 . ?
 C46 H46 0.9500 . ?
 C28 H28 0.9500 . ?
 C13 H13 0.9500 . ?
 C6 H6 0.9500 . ?
 C33 H33 0.9500 . ?
 C33 C34 1.377(8) . ?
 C58 H58A 0.9900 . ?
 C58 H58B 0.9900 . ?
 C34 H34 0.9500 . ?
 C57 H57A 0.9900 . ?
 C57 H57B 0.9900 . ?
 C59 H59A 0.9900 . ?
 C59 H59B 0.9900 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 Ag1 Pt1 Ag1 179.999(11) 2_666 . ?
 P2 Pt1 Ag1 91.27(2) . 2_666 ?
 P2 Pt1 Ag1 88.73(2) 2_666 2_666 ?
 P2 Pt1 Ag1 88.73(2) . . ?
 P2 Pt1 Ag1 91.27(2) 2_666 . ?
 P2 Pt1 P2 180.00(4) . 2_666 ?
 C37 Pt1 Ag1 58.42(11) . 2_666 ?
 C37 Pt1 Ag1 121.58(11) . . ?
 C37 Pt1 Ag1 58.42(11) 2_666 . ?
 C37 Pt1 Ag1 121.58(11) 2_666 2_666 ?
 C37 Pt1 P2 93.86(11) 2_666 . ?
 C37 Pt1 P2 86.14(11) . . ?
 C37 Pt1 P2 93.86(11) . 2_666 ?
 C37 Pt1 P2 86.14(11) 2_666 2_666 ?
 C37 Pt1 C37 180.00(18) . 2_666 ?
 P1 Ag1 Pt1 91.75(2) . . ?
 P1 Ag1 P3 156.41(4) . 2_666 ?
 P1 Ag1 C37 107.64(9) . 2_666 ?
 P3 Ag1 Pt1 91.93(2) 2_666 . ?
 P3 Ag1 C37 90.59(9) 2_666 2_666 ?
 C37 Ag1 Pt1 42.52(9) 2_666 . ?
 C17 P2 Pt1 122.91(14) . . ?
 C17 P2 C2 100.23(18) . . ?
 C17 P2 C1 108.16(19) . . ?
 C2 P2 Pt1 113.53(13) . . ?
 C2 P2 C1 103.01(17) . . ?
 C1 P2 Pt1 107.21(14) . . ?
 C29 P1 Ag1 111.33(14) . . ?
 C29 P1 C1 105.22(18) . . ?
 C1 P1 Ag1 108.84(13) . . ?
 C36 P1 Ag1 116.34(15) . . ?
 C36 P1 C29 109.13(19) . . ?
 C36 P1 C1 105.23(19) . . ?
 C2 P3 Ag1 106.52(13) . 2_666 ?
 C9 P3 Ag1 116.86(13) . 2_666 ?
 C9 P3 C2 103.05(18) . . ?
 C9 P3 C16 101.11(19) . . ?
 C16 P3 Ag1 121.20(16) . 2_666 ?
 C16 P3 C2 106.34(19) . . ?
 O3 Cl1 O1 108.4(3) . . ?
 O3 Cl1 O4 111.7(2) . . ?
 O1 Cl1 O4 108.8(2) . . ?
 O2 Cl1 O3 109.4(3) . . ?
 O2 Cl1 O1 109.1(4) . . ?
 O2 Cl1 O4 109.4(3) . . ?
 C24 C29 P1 119.7(3) . . ?
 C28 C29 P1 120.6(3) . . ?
 C28 C29 C24 119.4(4) . . ?
 C22 C17 P2 120.0(3) . . ?
 C18 C17 P2 118.5(3) . . ?
 C18 C17 C22 120.5(4) . . ?
 C17 C22 H22 120.3 . . ?
 C21 C22 C17 119.5(4) . . ?
 C21 C22 H22 120.3 . . ?
 P2 C2 P3 113.9(2) . . ?
 P2 C2 H2A 108.8 . . ?
 P2 C2 H2B 108.8 . . ?
 P3 C2 H2A 108.8 . . ?
 P3 C2 H2B 108.8 . . ?
 H2A C2 H2B 107.7 . . ?
 Pt1 C37 Ag1 79.06(13) . 2_666 ?
 C38 C37 Pt1 176.1(4) . . ?
 C38 C37 Ag1 98.9(3) . 2_666 ?
 C9 C8 H8 119.7 . . ?
 C7 C8 H8 119.7 . . ?
 C7 C8 C9 120.6(4) . . ?
 C8 C9 P3 121.4(3) . . ?
 C8 C9 C4 119.8(4) . . ?
 C4 C9 P3 118.8(3) . . ?
 C42 N1 C45 120.4(3) . . ?
 C42 N1 C51 120.9(3) . . ?
 C51 N1 C45 118.4(3) . . ?
 P2 C1 P1 113.2(2) . . ?
 P2 C1 H1A 108.9 . . ?
 P2 C1 H1B 108.9 . . ?
 P1 C1 H1A 108.9 . . ?
 P1 C1 H1B 108.9 . . ?
 H1A C1 H1B 107.8 . . ?
 C35 C36 P1 113.9(3) . . ?
 C31 C36 P1 126.0(4) . . ?
 C31 C36 C35 120.1(4) . . ?
 C39 C44 H44 119.1 . . ?
 C43 C44 H44 119.1 . . ?
 C43 C44 C39 121.7(4) . . ?
 C37 C38 C39 177.4(4) . . ?
 C17 C18 H18 120.3 . . ?
 C19 C18 C17 119.4(4) . . ?
 C19 C18 H18 120.3 . . ?
 C41 C42 N1 121.1(4) . . ?
 C43 C42 N1 121.0(4) . . ?
 C43 C42 C41 118.0(4) . . ?
 C44 C39 C38 120.9(4) . . ?
 C40 C39 C44 117.6(4) . . ?
 C40 C39 C38 121.5(4) . . ?
 C50 C45 N1 119.7(4) . . ?
 C50 C45 C46 119.4(4) . . ?
 C46 C45 N1 120.9(4) . . ?
 C52 C51 N1 120.8(4) . . ?
 C56 C51 N1 120.3(4) . . ?
 C56 C51 C52 118.9(4) . . ?
 C29 C24 C23 122.7(4) . . ?
 C25 C24 C29 118.4(4) . . ?
 C25 C24 C23 118.9(4) . . ?
 C22 C21 H21 120.3 . . ?
 C20 C21 C22 119.5(4) . . ?
 C20 C21 H21 120.3 . . ?
 C48 C49 H49 119.7 . . ?
 C48 C49 C50 120.7(4) . . ?
 C50 C49 H49 119.7 . . ?
 C18 C19 H19 119.8 . . ?
 C20 C19 C18 120.4(5) . . ?
 C20 C19 H19 119.8 . . ?
 C54 C55 H55 119.4 . . ?
 C54 C55 C56 121.2(4) . . ?
 C56 C55 H55 119.4 . . ?
 C36 C35 H35 119.9 . . ?
 C34 C35 C36 120.3(5) . . ?
 C34 C35 H35 119.9 . . ?
 C27 C26 H26 120.3 . . ?
 C27 C26 C25 119.5(4) . . ?
 C25 C26 H26 120.3 . . ?
 C55 C54 H54 120.6 . . ?
 C55 C54 C53 118.8(5) . . ?
 C53 C54 H54 120.6 . . ?
 C42 C41 H41 119.7 . . ?
 C40 C41 C42 120.6(4) . . ?
 C40 C41 H41 119.7 . . ?
 C4 C5 H5 119.1 . . ?
 C6 C5 H5 119.1 . . ?
 C6 C5 C4 121.8(4) . . ?
 C36 C31 C32 118.4(5) . . ?
 C36 C31 C30 123.4(5) . . ?
 C32 C31 C30 118.2(5) . . ?
 C31 C32 H32 120.2 . . ?
 C33 C32 C31 119.6(5) . . ?
 C33 C32 H32 120.2 . . ?
 C49 C48 H48 120.4 . . ?
 C49 C48 C47 119.2(4) . . ?
 C47 C48 H48 120.4 . . ?
 H10A C10 H10B 109.5 . . ?
 H10A C10 H10C 109.5 . . ?
 H10B C10 H10C 109.5 . . ?
 C11 C10 H10A 109.5 . . ?
 C11 C10 H10B 109.5 . . ?
 C11 C10 H10C 109.5 . . ?
 C26 C27 H27 119.9 . . ?
 C26 C27 C28 120.2(4) . . ?
 C28 C27 H27 119.9 . . ?
 C12 C11 C10 119.1(4) . . ?
 C16 C11 C10 123.6(5) . . ?
 C16 C11 C12 117.3(5) . . ?
 C11 C12 H12 120.0 . . ?
 C13 C12 C11 120.0(5) . . ?
 C13 C12 H12 120.0 . . ?
 C24 C23 H23A 109.5 . . ?
 C24 C23 H23B 109.5 . . ?
 C24 C23 H23C 109.5 . . ?
 H23A C23 H23B 109.5 . . ?
 H23A C23 H23C 109.5 . . ?
 H23B C23 H23C 109.5 . . ?
 C15 C14 H14 121.1 . . ?
 C15 C14 C13 117.9(5) . . ?
 C13 C14 H14 121.1 . . ?
 C48 C47 H47 119.7 . . ?
 C48 C47 C46 120.6(4) . . ?
 C46 C47 H47 119.7 . . ?
 H3A C3 H3B 109.5 . . ?
 H3A C3 H3C 109.5 . . ?
 H3B C3 H3C 109.5 . . ?
 C4 C3 H3A 109.5 . . ?
 C4 C3 H3B 109.5 . . ?
 C4 C3 H3C 109.5 . . ?
 C51 C52 H52 119.9 . . ?
 C53 C52 C51 120.3(4) . . ?
 C53 C52 H52 119.9 . . ?
 C54 C53 H53 119.6 . . ?
 C52 C53 C54 120.8(5) . . ?
 C52 C53 H53 119.6 . . ?
 C24 C25 H25 119.1 . . ?
 C26 C25 C24 121.8(4) . . ?
 C26 C25 H25 119.1 . . ?
 C31 C30 H30A 109.5 . . ?
 C31 C30 H30B 109.5 . . ?
 C31 C30 H30C 109.5 . . ?
 H30A C30 H30B 109.5 . . ?
 H30A C30 H30C 109.5 . . ?
 H30B C30 H30C 109.5 . . ?
 C14 C15 H15 119.5 . . ?
 C14 C15 C16 120.9(5) . . ?
 C16 C15 H15 119.5 . . ?
 C39 C40 H40 119.4 . . ?
 C41 C40 C39 121.3(4) . . ?
 C41 C40 H40 119.4 . . ?
 C21 C20 H20 119.6 . . ?
 C19 C20 C21 120.8(4) . . ?
 C19 C20 H20 119.6 . . ?
 C45 C50 C49 119.8(4) . . ?
 C45 C50 H50 120.1 . . ?
 C49 C50 H50 120.1 . . ?
 C8 C7 H7 120.3 . . ?
 C6 C7 C8 119.4(4) . . ?
 C6 C7 H7 120.3 . . ?
 C11 C16 P3 124.0(4) . . ?
 C11 C16 C15 120.2(4) . . ?
 C15 C16 P3 115.6(3) . . ?
 C44 C43 C42 120.7(4) . . ?
 C44 C43 H43 119.6 . . ?
 C42 C43 H43 119.6 . . ?
 C51 C56 H56 120.0 . . ?
 C55 C56 C51 120.1(4) . . ?
 C55 C56 H56 120.0 . . ?
 C9 C4 C3 122.3(4) . . ?
 C5 C4 C9 118.0(4) . . ?
 C5 C4 C3 119.7(4) . . ?
 C45 C46 H46 119.9 . . ?
 C47 C46 C45 120.2(4) . . ?
 C47 C46 H46 119.9 . . ?
 C29 C28 H28 119.6 . . ?
 C27 C28 C29 120.8(4) . . ?
 C27 C28 H28 119.6 . . ?
 C12 C13 C14 123.6(5) . . ?
 C12 C13 H13 118.2 . . ?
 C14 C13 H13 118.2 . . ?
 C5 C6 C7 120.4(4) . . ?
 C5 C6 H6 119.8 . . ?
 C7 C6 H6 119.8 . . ?
 C32 C33 H33 118.5 . . ?
 C32 C33 C34 123.0(5) . . ?
 C34 C33 H33 118.5 . . ?
 Cl6 C58 H58A 109.3 . . ?
 Cl6 C58 H58B 109.3 . . ?
 Cl7 C58 Cl6 111.8(3) . . ?
 Cl7 C58 H58A 109.3 . . ?
 Cl7 C58 H58B 109.3 . . ?
 H58A C58 H58B 107.9 . . ?
 C35 C34 H34 120.7 . . ?
 C33 C34 C35 118.6(5) . . ?
 C33 C34 H34 120.7 . . ?
 Cl3 C57 H57A 109.5 . . ?
 Cl3 C57 H57B 109.5 . . ?
 Cl2 C57 Cl3 110.6(3) . . ?
 Cl2 C57 H57A 109.5 . . ?
 Cl2 C57 H57B 109.5 . . ?
 H57A C57 H57B 108.1 . . ?
 Cl5 C59 H59A 109.4 . . ?
 Cl5 C59 H59B 109.4 . . ?
 Cl4 C59 Cl5 111.0(3) . . ?
 Cl4 C59 H59A 109.4 . . ?
 Cl4 C59 H59B 109.4 . . ?
 H59A C59 H59B 108.0 . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 Pt1 P2 C17 C22 23.4(4) . . . . ?
 Pt1 P2 C17 C18 -168.2(3) . . . . ?
 Pt1 P2 C2 P3 -51.3(2) . . . . ?
 Pt1 P2 C1 P1 64.0(2) . . . . ?
 Ag1 P1 C29 C24 69.1(4) . . . . ?
 Ag1 P1 C29 C28 -104.1(4) . . . . ?
 Ag1 P1 C1 P2 -43.2(2) . . . . ?
 Ag1 P1 C36 C35 11.5(4) . . . . ?
 Ag1 P1 C36 C31 -168.6(3) . . . . ?
 Ag1 P3 C2 P2 52.3(2) 2_666 . . . ?
 Ag1 P3 C9 C8 116.2(3) 2_666 . . . ?
 Ag1 P3 C9 C4 -62.9(4) 2_666 . . . ?
 Ag1 P3 C16 C11 8.8(4) 2_666 . . . ?
 Ag1 P3 C16 C15 -175.1(2) 2_666 . . . ?
 P2 C17 C22 C21 167.7(3) . . . . ?
 P2 C17 C18 C19 -168.3(3) . . . . ?
 P1 C29 C24 C23 6.2(6) . . . . ?
 P1 C29 C24 C25 -173.7(3) . . . . ?
 P1 C29 C28 C27 172.5(4) . . . . ?
 P1 C36 C35 C34 179.8(4) . . . . ?
 P1 C36 C31 C32 178.9(4) . . . . ?
 P1 C36 C31 C30 -0.3(7) . . . . ?
 P3 C9 C4 C5 179.4(3) . . . . ?
 P3 C9 C4 C3 -2.0(6) . . . . ?
 C29 P1 C1 P2 -162.6(2) . . . . ?
 C29 P1 C36 C35 138.5(3) . . . . ?
 C29 P1 C36 C31 -41.6(4) . . . . ?
 C29 C24 C25 C26 0.9(7) . . . . ?
 C17 P2 C2 P3 81.6(2) . . . . ?
 C17 P2 C1 P1 -70.5(3) . . . . ?
 C17 C22 C21 C20 0.3(6) . . . . ?
 C17 C18 C19 C20 0.6(7) . . . . ?
 C22 C17 C18 C19 0.1(6) . . . . ?
 C22 C21 C20 C19 0.4(7) . . . . ?
 C2 P2 C17 C22 -103.5(3) . . . . ?
 C2 P2 C17 C18 64.9(3) . . . . ?
 C2 P2 C1 P1 -176.0(2) . . . . ?
 C2 P3 C9 C8 -0.2(4) . . . . ?
 C2 P3 C9 C4 -179.3(3) . . . . ?
 C2 P3 C16 C11 130.4(4) . . . . ?
 C2 P3 C16 C15 -53.5(3) . . . . ?
 C8 C9 C4 C5 0.4(6) . . . . ?
 C8 C9 C4 C3 179.0(4) . . . . ?
 C8 C7 C6 C5 0.6(7) . . . . ?
 C9 P3 C2 P2 175.9(2) . . . . ?
 C9 P3 C16 C11 -122.3(4) . . . . ?
 C9 P3 C16 C15 53.8(3) . . . . ?
 C9 C8 C7 C6 -1.3(7) . . . . ?
 N1 C42 C41 C40 -179.8(4) . . . . ?
 N1 C42 C43 C44 179.8(4) . . . . ?
 N1 C45 C50 C49 -178.3(4) . . . . ?
 N1 C45 C46 C47 178.9(4) . . . . ?
 N1 C51 C52 C53 179.1(4) . . . . ?
 N1 C51 C56 C55 -178.7(4) . . . . ?
 C1 P2 C17 C22 149.1(3) . . . . ?
 C1 P2 C17 C18 -42.5(4) . . . . ?
 C1 P2 C2 P3 -166.9(2) . . . . ?
 C1 P1 C29 C24 -173.1(3) . . . . ?
 C1 P1 C29 C28 13.6(4) . . . . ?
 C1 P1 C36 C35 -109.0(3) . . . . ?
 C1 P1 C36 C31 70.8(4) . . . . ?
 C36 P1 C29 C24 -60.6(4) . . . . ?
 C36 P1 C29 C28 126.1(4) . . . . ?
 C36 P1 C1 P2 82.2(3) . . . . ?
 C36 C35 C34 C33 1.5(8) . . . . ?
 C36 C31 C32 C33 1.1(7) . . . . ?
 C44 C39 C40 C41 -0.8(6) . . . . ?
 C38 C39 C40 C41 177.2(4) . . . . ?
 C18 C17 C22 C21 -0.5(6) . . . . ?
 C18 C19 C20 C21 -0.9(7) . . . . ?
 C42 N1 C45 C50 -136.4(4) . . . . ?
 C42 N1 C45 C46 45.3(6) . . . . ?
 C42 N1 C51 C52 46.7(6) . . . . ?
 C42 N1 C51 C56 -134.2(4) . . . . ?
 C42 C41 C40 C39 0.1(7) . . . . ?
 C39 C44 C43 C42 -0.1(6) . . . . ?
 C45 N1 C42 C41 33.7(6) . . . . ?
 C45 N1 C42 C43 -146.9(4) . . . . ?
 C45 N1 C51 C52 -139.9(4) . . . . ?
 C45 N1 C51 C56 39.2(6) . . . . ?
 C51 N1 C42 C41 -153.1(4) . . . . ?
 C51 N1 C42 C43 26.3(6) . . . . ?
 C51 N1 C45 C50 50.1(5) . . . . ?
 C51 N1 C45 C46 -128.1(4) . . . . ?
 C51 C52 C53 C54 0.1(8) . . . . ?
 C24 C29 C28 C27 -0.8(7) . . . . ?
 C49 C48 C47 C46 0.3(7) . . . . ?
 C55 C54 C53 C52 -0.6(8) . . . . ?
 C35 C36 C31 C32 -1.2(7) . . . . ?
 C35 C36 C31 C30 179.5(4) . . . . ?
 C26 C27 C28 C29 1.5(8) . . . . ?
 C54 C55 C56 C51 -0.9(8) . . . . ?
 C41 C42 C43 C44 -0.7(6) . . . . ?
 C31 C36 C35 C34 0.0(7) . . . . ?
 C31 C32 C33 C34 0.4(9) . . . . ?
 C32 C33 C34 C35 -1.7(9) . . . . ?
 C48 C49 C50 C45 -0.4(7) . . . . ?
 C48 C47 C46 C45 -0.8(7) . . . . ?
 C10 C11 C12 C13 -179.4(5) . . . . ?
 C10 C11 C16 P3 -5.0(6) . . . . ?
 C10 C11 C16 C15 179.1(4) . . . . ?
 C27 C26 C25 C24 -0.3(8) . . . . ?
 C11 C12 C13 C14 0.4(8) . . . . ?
 C12 C11 C16 P3 174.7(3) . . . . ?
 C12 C11 C16 C15 -1.2(6) . . . . ?
 C23 C24 C25 C26 -179.0(5) . . . . ?
 C14 C15 C16 P3 -175.8(3) . . . . ?
 C14 C15 C16 C11 0.5(6) . . . . ?
 C52 C51 C56 C55 0.4(7) . . . . ?
 C25 C26 C27 C28 -0.9(8) . . . . ?
 C30 C31 C32 C33 -179.6(5) . . . . ?
 C15 C14 C13 C12 -1.2(7) . . . . ?
 C50 C45 C46 C47 0.6(7) . . . . ?
 C50 C49 C48 C47 0.3(7) . . . . ?
 C7 C8 C9 P3 -178.3(3) . . . . ?
 C7 C8 C9 C4 0.7(6) . . . . ?
 C16 P3 C2 P2 -78.2(3) . . . . ?
 C16 P3 C9 C8 -110.1(4) . . . . ?
 C16 P3 C9 C4 70.9(4) . . . . ?
 C16 C11 C12 C13 0.8(7) . . . . ?
 C43 C44 C39 C38 -177.2(4) . . . . ?
 C43 C44 C39 C40 0.9(6) . . . . ?
 C43 C42 C41 C40 0.7(6) . . . . ?
 C56 C51 C52 C53 0.0(7) . . . . ?
 C56 C55 C54 C53 1.0(8) . . . . ?
 C4 C5 C6 C7 0.5(7) . . . . ?
 C46 C45 C50 C49 -0.1(7) . . . . ?
 C28 C29 C24 C23 179.5(4) . . . . ?
 C28 C29 C24 C25 -0.4(6) . . . . ?
 C13 C14 C15 C16 0.8(7) . . . . ?
 C6 C5 C4 C9 -1.0(7) . . . . ?
 C6 C5 C4 C3 -179.7(4) . . . . ?

_olex2_submission_special_instructions  'No special instructions were received'
