[3 + 2]-Cycloaddition of Azaoxyallyl Cations with
Hexahydro-1,3,5-triazines: Access to 4‑Imidazolidinones
Posted on 2018-04-20 - 17:03
A novel
base-promoted [3 + 2] cycloaddition reaction of azaoxyallyl
cations with hexahydro-1,3,5-triazines has been developed, affording
4-imidazolidinones in moderate to good yields under mild reaction
conditions. This simple but efficient protocol features cycloaddition
of two in situ formed reactive species in the absence of a transition-metal
catalyst.
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Ji, Danqing; Sun, Jiangtao (2018). [3 + 2]-Cycloaddition of Azaoxyallyl Cations with
Hexahydro-1,3,5-triazines: Access to 4‑Imidazolidinones. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.8b00951
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