Understanding and Interrupting the Fischer Azaindolization
Reaction

Garg, Neil K.

Understanding and Interrupting the Fischer Azaindolization Reaction

Posted on 2017-10-12 - 12:05

Experimental and computational studies pertaining to the Fischer azaindolization reaction are reported. These studies explain why pyridylhydrazines are poorly reactive in Fischer indolization reactions, in addition to the origin of hydrazine substituent effects. Additionally, an interrupted variant of Fischer azaindolization methodology is disclosed, which provides a synthetic entryway into fused azaindoline scaffolds.

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Simmons, Bryan J.; Hoffmann, Marie; Champagne, Pier Alexandre; Picazo, Elias; Yamakawa, Katsuya; Morrill, Lucas A.; et al. (2017). Understanding and Interrupting the Fischer Azaindolization Reaction. ACS Publications. Collection. https://doi.org/10.1021/jacs.7b07518

https://doi.org/10.1021/jacs.7b07518

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