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Ultrafine TiO2 Confined in Porous-Nitrogen-Doped Carbon from Metal–Organic Frameworks for High-Performance Lithium Sulfur Batteries

Posted on 2017-03-30 - 16:19
Ultrafine TiO2 confined in porous-nitrogen-doped carbon is synthesized from a single metal–organic framework precursor. As a novel interlayer for lithium–sulfur batteries, the TiO2@NC composite can act as both a high efficiency lithium polysulfide barrier to suppress the side reactions and an additional current collector to enhance the polysulfide redox reactions. The lithium–sulfur battery with a TiO2@NC interlayer delivers a high reversible capacity of 1460 mAh g–1 at 0.2 C and capacity retention of 71% even after 500 cycles with high rate capability.

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