Synthesis and Structure of the First Heterodinuclear PCP−Pincer−CDP Complex with a Pd−Au d8−d10 Pseudo-Closed-Shell Interaction
Posted on 2009-11-23 - 00:00
The first heterodimetallic PCP pincer complex, [PdAu(Cl)2(C(dppm)2)]Cl, was prepared from [PdCl(C(dppm)2)]Cl and [AuCl(tht)]. Both metals are attached to the carbon atom of the carbodiphosphorane (CDP) functionality and are connected via a very short d8−d10 pseudo-closed-shell interaction (Pd−Au = 2.8900(3) Å) which significantly modifies the ligand backbone conformation.
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Reitsamer, Christian; Schuh, Walter; Kopacka, Holger; Wurst, Klaus; Peringer, Paul (2016). Synthesis and Structure of the First Heterodinuclear PCP−Pincer−CDP Complex with a Pd−Au d8−d10 Pseudo-Closed-Shell Interaction. ACS Publications. Collection. https://doi.org/10.1021/om900686r
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AUTHORS (5)
- CRChristian ReitsamerWSWalter SchuhHKHolger KopackaKWKlaus WurstPPPaul Peringer
