Synthesis and Properties of V6O16Cu(C4H4N2)2·(H2O)0.22(1):
Charge Density Matching of a Metal-Segregated Layer Structure
Posted on 2003-06-18 - 00:00
A metal-segregated layered compound, containing square nets of
Cu(pyz)22+ and buckled V6O162- layers, has been synthesized using
hydrothermal techniques to have the composition V6O16Cu(C4H4N2)2·(H2O)0.22(1) (C4H4N2 = pyrazine, pyz). The Cu(II) square
nets are nearly regular and undergo an antiferromagnetic transition
at 8 K. In contrast to the plethora of recently synthesized metal−oxide clusters, chains, and networks in the VOx/M/L (M = late
transition element; L = organonitrogen ligand) system, this
compound is a relatively rare example that contains two different
metals distributed into distinct layers. An application of charge
density matching to form layered structures is postulated.
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Maggard, Paul A.; Boyle, Paul D. (2016). Synthesis and Properties of V6O16Cu(C4H4N2)2·(H2O)0.22(1):
Charge Density Matching of a Metal-Segregated Layer Structure. ACS Publications. Collection. https://doi.org/10.1021/ic0342649
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