Synthesis and Enhanced Linear and Nonlinear Optical
Properties of Chromophore–Au Metal Cluster Oligomers
Version 2 2018-01-22, 19:51
Version 1 2018-01-22, 19:45
Posted on 2018-01-22 - 19:51
Using nanoclusters
as building blocks for supracrystals can offer
unique optical and electronic properties of metal nanoclusters for
designing new materials. The advantage of building nanocluster crystals
through molecular linkers is that the linker can be used as a functional
group for the nanoclusters (e.g., dye–nanocluster systems).
In this study, we employed the ligand exchange reaction to synthesize
chromophore–Au25 nanocluster oligomers and investigated
their linear and nonlinear optical properties. The chromophore–Au25 nanocluster oligomers product mixture was separated into
four bands by polyacrylamide gel electrophoresis and characterized
by matrix-assisted laser desorption ionization mass spectrometry and
scanning transmission electron microscopy imaging. The linear optical
properties of the systems were investigated by steady state UV–vis
absorption and fluorescence spectroscopy. The chromophore–Au25 nanocluster oligomers showed increased oscillator strength
and transition dipole moment compared to single Au25 nanoclusters.
Energy transfer from the chromophore 4,4′-thiodibenzenethiol
(TBT) to the metal cluster was observed in the chromophore–Au25 nanocluster dimer system. The excited state and fluorescence
dynamics were investigated by transient absorption spectroscopy, time-resolved
fluorescence upconversion, and time-correlated single photon counting.
The chromophore–Au25 nanocluster oligomers have
a long-lived surface state due to the contribution of energy transfer
by two nanocluster cores. The two-photon absorption cross sections
of the chromophore–Au25 nanocluster oligomers showed
an increasing enhancement trend with increasing oligomer length. An
enhancement factor of up to 68 times was found compared to single
Au25 nanoclusters. Finally, we performed a structure–property
correlation analysis to explain the observed optical properties of
these systems.
CITE THIS COLLECTION
DataCite
3 Biotech
3D Printing in Medicine
3D Research
3D-Printed Materials and Systems
4OR
AAPG Bulletin
AAPS Open
AAPS PharmSciTech
Abhandlungen aus dem Mathematischen Seminar der Universität Hamburg
ABI Technik (German)
Academic Medicine
Academic Pediatrics
Academic Psychiatry
Academic Questions
Academy of Management Discoveries
Academy of Management Journal
Academy of Management Learning and Education
Academy of Management Perspectives
Academy of Management Proceedings
Academy of Management Review
Ho-Wu, Rosina; Sun, Kai; Goodson, Theodore (2018). Synthesis and Enhanced Linear and Nonlinear Optical
Properties of Chromophore–Au Metal Cluster Oligomers. ACS Publications. Collection. https://doi.org/10.1021/acs.jpcc.7b11480
or
Select your citation style and then place your mouse over the citation text to select it.
SHARE
Usage metrics
Read the peer-reviewed publication
AUTHORS (3)
RH
Rosina Ho-Wu
KS
Kai Sun
TG
Theodore Goodson
KEYWORDS
Nonlinear Optical Propertieschromophoretime-resolved fluorescence upconversion25 nanoclustersTBTpolyacrylamide gel electrophoresisscanning transmission electron microscopy imagingbuilding nanocluster crystalsmatrix-assisted laser desorption ionization mass spectrometryUVligand exchange reactionoligomerenergy transfer