Synthesis and Crystal Structures of the First Antimony(III)
Aziridinides

Edelmann, Frank T.

Synthesis and Crystal Structures of the First Antimony(III) Aziridinides

Posted on 2017-03-25 - 20:48

The first antimony(III) aziridinyl derivatives are reported. Treatment of anhydrous SbCl₃ with N-lithioaziridine Li(Azn) (Azn = NC₂H₄) afforded the structurally unique heterobimetallic lithium/antimony(III) amide complex [Li₃Sb(μ₃-Cl)₂(μ-Azn)₄(THF)₂]_∞ (1). Homoleptic Sb₂(Azn)₆ (2) has become available for the first time through an amide group exchange reaction between Sb(NMe₂)₃ and 3 equiv of aziridine. The low-melting Sb₂(Azn)₆ exhibits a “weak dimer” structure in the crystal.

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Harmgarth, Nicole; Liebing, Phil; Zörner, Florian; Silinskas, Mindaugas; Burte, Edmund P.; Edelmann, Frank T. (2017). Synthesis and Crystal Structures of the First Antimony(III) Aziridinides. ACS Publications. Collection. https://doi.org/10.1021/acs.inorgchem.7b00523

https://doi.org/10.1021/acs.inorgchem.7b00523

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