Synthesis, Emission, and Electrochemical Properties of Luminescent Dinuclear Zinc(II)
Chalcogenolate Complexes. Dynamic 1H NMR Studies and X-ray Crystal Structure of
[(bpy)Zn2(SC6H4-Cl-p)(μ-SC6H4-Cl-p)(μ-OAc)2]
Posted on 2000-11-15 - 00:00
A series of novel luminescent dinuclear zinc(II) diimine complexes with bridging chalcogenolate ligands have
been synthesized, in which the two zinc atoms were found to exist in different coordination environment. The
luminescence and electrochemical behavior of these complexes have been studied. These complexes have also
been shown to exhibit dynamic fluxional behavior in solution due to an exchange of the bridging and terminal
thiolate ligands. The mechanism and kinetics of which have been investigated by variable-temperature 1H NMR
studies. The X-ray crystal structure of [(bpy)Zn2(SC6H4-Cl-p)(μ-SC6H4-Cl-p)(μ-OAc)2] has also been determined.
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Yam, Vivian Wing-Wah; Pui, Yung-Lin; Cheung, Kung-Kai (2016). Synthesis, Emission, and Electrochemical Properties of Luminescent Dinuclear Zinc(II)
Chalcogenolate Complexes. Dynamic 1H NMR Studies and X-ray Crystal Structure of
[(bpy)Zn2(SC6H4-Cl-p)(μ-SC6H4-Cl-p)(μ-OAc)2]. ACS Publications. Collection. https://doi.org/10.1021/ic000688g
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