Spiroschincarins A–E: Five Spirocyclic Nortriterpenoids
from the Fruit of Schisandra incarnata

Ruan, Han-Li

Spiroschincarins A–E: Five Spirocyclic Nortriterpenoids from the Fruit of Schisandra incarnata

Version 3 2017-02-20, 18:04

Version 2 2017-02-17, 19:24

Version 1 2017-02-16, 18:20

Posted on 2017-02-20 - 18:04

Spiroschincarins A–E (1–5), five novel spirocyclic schinortriterpenoids featuring a unique 1-oxaspiro[6.6]tridecane motif, were isolated from the fruit of Schisandra incarnata. Their structures with absolute configurations were determined by extensive spectroscopic analyses, single-crystal X-ray diffractions, and experimental ECD (electronic circular dichroism). A hypothetical biogenetic pathway of 1–5 was postulated.

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Song, Jian; Liu, Ye; Zhou, Ming; Cao, Hui; Peng, Xiao-Gang; Liang, Jing-Jing; et al. (2017). Spiroschincarins A–E: Five Spirocyclic Nortriterpenoids from the Fruit of Schisandra incarnata. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b00250

https://doi.org/10.1021/acs.orglett.7b00250

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