Selective Synthesis of Diaryl Sulfoxides and m‑Arylthio Sulfones from Arylsulfinic Acids and Arenes
via BF3‑Promoted C–S Bond Formation
Posted on 2018-07-13 - 19:44
A novel and efficient
method for selective synthesis of diaryl
sulfoxides and m-arylthio sulfones has been achieved
from readily available arylsulfinic acids and arenes via an unusual
sulfinyl cation, providing a range of structurally diverse products
in good to excellent yields under mild conditions. Notably, mechanistic
investigations suggested m-arylthio sulfones were
generated from diaryl sulfoxides and sulfinyl cation by a sequence
of redox reaction and electrophilic aromatic substitution process.
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Shi, Wei; Miao, Tao; Li, Yang; Li, Pinhua; Wang, Lei (2018). Selective Synthesis of Diaryl Sulfoxides and m‑Arylthio Sulfones from Arylsulfinic Acids and Arenes
via BF3‑Promoted C–S Bond Formation. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.8b01681
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AUTHORS (5)
WS
Wei Shi
TM
Tao Miao
YL
Yang Li
PL
Pinhua Li
LW
Lei Wang