Ruthenium-Catalyzed
Cycloisomerization of 2‑Alkynylanilides:
Synthesis of 3‑Substituted Indoles by 1,2-Carbon Migration

Saito, Shinichi

Ruthenium-Catalyzed Cycloisomerization of 2‑Alkynylanilides: Synthesis of 3‑Substituted Indoles by 1,2-Carbon Migration

Version 2 2017-06-19, 04:29

Version 1 2017-06-01, 17:34

Posted on 2017-06-19 - 04:29

We developed ruthenium-catalyzed cycloisomerization of alkynylanilides that gave 3-substituted indoles in high yields. The reaction proceeded via the disubstituted vinylidene ruthenium complex that was formed by the 1,2-carbon migration.

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Watanabe, Takuma; Mutoh, Yuichiro; Saito, Shinichi (2017). Ruthenium-Catalyzed Cycloisomerization of 2‑Alkynylanilides: Synthesis of 3‑Substituted Indoles by 1,2-Carbon Migration. ACS Publications. Collection. https://doi.org/10.1021/jacs.7b04564

https://doi.org/10.1021/jacs.7b04564

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