Regioselective Synthesis of Asymmetrically Substituted
2-Quinoxalinol Salen Ligands

Vilseck, Jonah Z.

Regioselective Synthesis of Asymmetrically Substituted 2-Quinoxalinol Salen Ligands

Posted on 2007-11-09 - 00:00

Diamino-2-quinoxalinols are reacted with salicylaldehyde derivatives to produce 2-quinoxalinol imines regioselectively as one isomer in good yield. Regioselectivity has been determined through the use of isotopic ¹⁵N labeling experiments. The 2-quinoxalinol imines may then be reacted without further purification with additional salicylaldehyde derivatives to yield asymmetrically substituted 2-quinoxalinol salens.

CITE THIS COLLECTION

Wu, Xianghong; E. V. Gorden, Anne; Tonks, Stephen A.; Vilseck, Jonah Z. (2016). Regioselective Synthesis of Asymmetrically Substituted 2-Quinoxalinol Salen Ligands. ACS Publications. Collection. https://doi.org/10.1021/jo701395w

https://doi.org/10.1021/jo701395w

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