Pseudo-2D Porous Networks via Interpenetration of
1D Zigzag Ladder-type Coordination Polymers: Adsorption and Separation
of Xylene Isomers
Posted on 2020-04-10 - 10:43
Self-assembly of AgPF6 with a new C3-symmetric tridentate N-donor ligand
gives rise to unusual pseudo-2D porous networks with open channels
via the interpenetration of 1D zigzag ladders. The open-channel networks
selectively adsorb only m-xylene from the mixture
of o- and m-xylene, with o-xylene thus acting as a channel-entrance stopper at room
temperature. This system exemplifies unprecedented separation of o- and m-xylene.
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Lee, Soojin; Kim, Dongwon; Kim, Junhee; Jung, Ok-Sang (2020). Pseudo-2D Porous Networks via Interpenetration of
1D Zigzag Ladder-type Coordination Polymers: Adsorption and Separation
of Xylene Isomers. ACS Publications. Collection. https://doi.org/10.1021/acs.cgd.0c00336
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