Preparation of Organic Nitrates from Aryldiazoacetates
and Fe(NO3)3·9H2O
Posted on 2019-08-21 - 16:07
A thermal protocol
is reported for the formal insertion of nitric
acid into aryldiazoacetates using Fe(NO3)3·9H2O. This strategy is mild and high yielding and allows the
preparation of a large variety of members of an unprecedented family
of organic nitrates. The nitrate group can be also readily transformed
into other functional groups and heterocyclic moieties and can possibly
allow new biological explorations of untapped potential associated
with their NO-releasing ability.
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Thurow, Samuel; Fernandes, Alessandra A. G.; Quevedo-Acosta, Yovanny; de Oliveira, Matheus F.; de Oliveira, Marcelo G.; Jurberg, Igor D. (2019). Preparation of Organic Nitrates from Aryldiazoacetates
and Fe(NO3)3·9H2O. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.9b02522
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AUTHORS (6)
- STSamuel ThurowAFAlessandra A. G. FernandesYQYovanny Quevedo-AcostaMdMatheus F. de OliveiraMdMarcelo G. de OliveiraIJIgor D. Jurberg
