Phosphorus-Containing Bis-allenes: Synthesis and Heterocyclization
Reactions Mediated by Iodine or Copper Dibromide
Posted on 2017-03-29 - 21:13
Bisphosphorylallenes
were easily obtained in multigram scale from
the Wittig-type rearrangement of bispropargyl alcohols. Unlike other
conjugated bis-allenes, these reagents underwent a double cyclization
mediated by iodine or copper dibromide leading to the formation of
bis-1,2-oxaphospholenes.
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Essid, I.; Laborde, C.; Legros, F.; Sevrain, N.; Touil, S.; Rolland, M.; et al. (2017). Phosphorus-Containing Bis-allenes: Synthesis and Heterocyclization
Reactions Mediated by Iodine or Copper Dibromide. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b00648
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AUTHORS (10)
IE
I. Essid
CL
C. Laborde
FL
F. Legros
NS
N. Sevrain
ST
S. Touil
MR
M. Rolland
TA
T. Ayad
JV
J.-N. Volle
JP
J.-L. Pirat
DV
D. Virieux