Palladium-Catalyzed Saegusa–Ito
Oxidation:
Synthesis of α,β-Unsaturated Carbonyl Compounds from Trimethylsilyl
Enol Ethers

Lebel, Hélène

Palladium-Catalyzed Saegusa–Ito Oxidation: Synthesis of α,β-Unsaturated Carbonyl Compounds from Trimethylsilyl Enol Ethers

Posted on 2016-02-20 - 01:13

Palladium-catalyzed Saegusa–Ito oxidation of trimethylsilyl enol ethers is possible using Oxone as a stoichiometric oxidant and sodium hydrogen phosphate as a buffer. Cyclic and acyclic enones as well as α,β-unsaturated aldehydes are obtained in good to excellent yields.

CITE THIS COLLECTION

Lu, Yingdong; Nguyen, Pierre Long; Lévaray, Nicolas; Lebel, Hélène (2016). Palladium-Catalyzed Saegusa–Ito Oxidation: Synthesis of α,β-Unsaturated Carbonyl Compounds from Trimethylsilyl Enol Ethers. ACS Publications. Collection. https://doi.org/10.1021/jo302465v

https://doi.org/10.1021/jo302465v

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