Palladium-Catalyzed Decarbonylative Alkynylation of
Amides
Posted on 2018-04-20 - 16:49
A palladium-catalyzed
decarbonylative alkynylation of amides via
C–N bond activation is developed. Compared with the reported
Ni/Cu catalyzed reaction, which only proceeded well with silylacetylenes,
this transformation was also applicable to both aromatic and aliphatic
terminal alkynes, including those bearing functional groups, and thus
provided a general and straightforward access to diverse internal
alkynes.
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Liu, Long; Zhou, Dan; Liu, Min; Zhou, Yongbo; Chen, Tieqiao (2018). Palladium-Catalyzed Decarbonylative Alkynylation of
Amides. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.8b00949
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AUTHORS (5)
LL
Long Liu
DZ
Dan Zhou
ML
Min Liu
YZ
Yongbo Zhou
TC
Tieqiao Chen