NCN-Type Pincer Complexes of Subporphyrinatoboron(III)

Osuka, Atsuhiro

NCN-Type Pincer Complexes of Subporphyrinatoboron(III)

Posted on 2017-05-26 - 20:43

The first NCN-type subporphyrin pincer complexes 3Pd and 3Pt have been synthesized via Suzuki coupling of 2,13-diborylsubporphyrin with 2-iodopyridine, followed by metalation with PdCl₂(MeCN)₂ or K₂PtCl₄, respectively. 2,13-Diiminosubporphyrin 4 was also prepared via formylation of 2,13-dilithiosubporphyrin followed by imination with aniline but was found to be unsuitable as a precursor of organometallic species. The complexes 3Pd and 3Pt displayed perturbed optical properties presumably due to the d(metal)π(subporphyrin) orbital interactions.

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Kitano, Masaaki; Tanaka, Takayuki; Osuka, Atsuhiro (2017). NCN-Type Pincer Complexes of Subporphyrinatoboron(III). ACS Publications. Collection. https://doi.org/10.1021/acs.organomet.7b00130

https://doi.org/10.1021/acs.organomet.7b00130

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