Multiarm Polycarbonate Star Polymers with a Hyperbranched
Polyether Core from CO2 and Common Epoxides
Version 2 2017-08-21, 18:56
Version 1 2017-08-21, 18:53
Posted on 2017-08-21 - 18:56
Multiarm star copolymers, consisting
of hyperbranched poly(ethylene
oxide) (hbPEO) or poly(butylene oxide) (hbPBO) polyether copolymers with glycerol branching points as a core,
and linear aliphatic polycarbonate arms generated from carbon dioxide
(CO2) and epoxide monomers, were synthesized via a “core-first”
approach in two steps. First, hyperbranched polyether polyols were
prepared by anionic copolymerization of ethylene oxide or 1,2-butylene
oxide with 8–35% glycidol with molecular weights between 800
and 389,000 g·mol–1. Second, multiple arms
were grown via immortal copolymerization of CO2 with propylene
oxide or 1,2-butylene oxide using the polyether polyols as macroinitiators
and (R,R)-(salcy)-CoCl as a catalyst
in a solvent-free procedure. Molecular weights up to 812,000 g·mol–1 were obtained for the resulting multiarm polycarbonates,
determined by online viscometry with universal calibration and 1H NMR. Comparing the synthesis of different multiarm star
polycarbonates, a combination of a highly reactive macroinitiator
with a less reactive epoxide monomer was found to be most suitable
to obtain well-defined structures containing up to 88 mol% polycarbonate.
The multiarm star copolymers were investigated with respect to their
thermal properties, intrinsic viscosity, and potential application
as polyols for polyurethane synthesis. Glass transition temperatures
in the range from −41 to +25 °C were observed. The intrinsic
viscosity could be adjusted between 5.4 and 17.3 cm3·g–1 by varying the ratio of polyether units and polycarbonate
units.
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Scharfenberg, Markus; Seiwert, Jan; Scherger, Maximilian; Preis, Jasmin; Susewind, Moritz; Frey, Holger (2017). Multiarm Polycarbonate Star Polymers with a Hyperbranched
Polyether Core from CO2 and Common Epoxides. ACS Publications. Collection. https://doi.org/10.1021/acs.macromol.7b01131
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AUTHORS (6)
MS
Markus Scharfenberg
JS
Jan Seiwert
MS
Maximilian Scherger
JP
Jasmin Preis
MS
Moritz Susewind
HF
Holger Frey