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Mono- and Dihydroxylated Symmetrical Octamethylcucurbiturils and Allylated Derivatives

Version 2 2016-10-31, 17:00
Version 1 2016-10-21, 18:23
Posted on 2016-10-21 - 00:00
Mono- and dihydroxylated symmetrical octa­meth­yl­cu­cur­bit­[6]­urils {(OH)­OMeQ[6] and (OH)2OMeQ­[6]} were prepared using a photochemical method to introduce limited alcohol group(s) directly to the parent symmetrical octamethylcucurbit[6]­uril (OMeQ[6]), and the resulting compounds were verified by 1H NMR, Xevo Q-TOF MS, and X-ray crystallography. Further chemical modification of mono- and dihydroxylated OMeQ[6] was also performed.

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