Molecular Engineering of D−π–A Type of Blue-Colored Dyes for Highly Efficient Solid-State Dye-Sensitized Solar Cells through Co-Sensitization

Published on 2018-11-08T18:21:23Z (GMT) by
A novel blue-colored organic donor-π-acceptor sensitizer, the so-called MKA16 dye, has been employed to construct solid-state dye-sensitized solar cells (ssDSSCs). Using 2,2′,7-,7′-tetrakis­(<i>N</i>,<i>N</i>-di-<i>p</i>-methoxyphenyl-amine) 9,9′-spirobifuorene (Spiro-OMeTAD) as hole-transport material, a good conversion efficiency of 5.8% was recorded for cells based on the MKA16 dye and a high photovoltage of 840 mV in comparison with 5.6% efficiency using the known (Dyenamo Blue) dye. By co-sensitization using the orange-colored D35 dye and MKA16 together, the solid-state solar cells showed an excellent efficiency of 7.5%, with a high photocurrent of 12.41 mA cm<sup>–2</sup> and open-circuit voltage of 850 mV. The results show that the photocurrent of ssDSSCs can be significantly improved by co-sensitization mainly attributed to the wider light absorption range contributing to the photocurrent. In addition, results from photo-induced absorption spectroscopy show that the dye regeneration is efficient in co-sensitized solar cells. The current results possible routes of improving the design of aesthetic and highly efficient ssDSSCs.

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Liu, Peng; Wang, Linqin; Karlsson, Karl Martin; Hao, Yan; Gao, Jiajia; Xu, Bo; et al. (2018): Molecular Engineering of D−π–A

Type of Blue-Colored Dyes for Highly Efficient Solid-State Dye-Sensitized

Solar Cells through Co-Sensitization. ACS Publications. Collection.