Mechanochemical Post-Polymerization Modification:
Solvent-Free Solid-State Synthesis of Functional Polymers
Posted on 2018-04-20 - 18:20
Mechanochemical
postpolymerization modification is reported herein.
The fast and efficient synthesis of a library of macromolecules with
functional diversity and structural uniformity was realized without
a solvent by means of a high speed ball-milling technique. A series
of polymers prepared from 4-vinylbenzaldehyde (4-VBA) underwent solid-state
Schiff base formations with a series of amines and amine derivatives.
The efficient mixing and energy delivery provided by the collisions
between balls not only promoted rapid imine formation but also eliminated
the need for a chemical solvent, which is highly desirable for green
chemical synthesis.
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Ohn, Nuri; Kim, Jeung Gon (2018). Mechanochemical Post-Polymerization Modification:
Solvent-Free Solid-State Synthesis of Functional Polymers. ACS Publications. Collection. https://doi.org/10.1021/acsmacrolett.8b00171
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AUTHORS (2)
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Nuri Ohn
JK
Jeung Gon Kim
KEYWORDS
VBAamine derivativesSolvent-Free Solid-State Synthesisseriesvinylbenzaldehydeuniformitychemical synthesisFunctional Polymers Mechanochemical postpolymerization modification4-imine formationenergy deliveryMechanochemical Post-Polymerization Modificationdiversityaminesspeed ball-milling techniquemacromoleculesSchiff base formations