Markovnikov-Selective Co(I)-Catalyzed Hydroboration
of Vinylarenes and Carbonyl Compounds
Posted on 2018-12-10 - 19:19
An NHC-supported
Co(I) catalyst has been developed for selective
Markovnikov hydroboration of vinylarenes under mild reaction conditions.
The hydroboration allows highly selective synthesis of a wide range
of secondary and tertiary alkyl boronates in excellent yields. Our
protocol also enables hydroboration of aldehydes and ketones with
diverse functional groups to access the corresponding borate esters.
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Verma, Piyush
Kumar; A. S., Sethulekshmi; Geetharani, K. (2018). Markovnikov-Selective Co(I)-Catalyzed Hydroboration
of Vinylarenes and Carbonyl Compounds. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.8b03356
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AUTHORS (3)
PV
Piyush
Kumar Verma
SA
Sethulekshmi A. S.
KG
K. Geetharani