K2Hg2Te3: Straightforward
and Large-Scale Mercury-Flux Synthesis of a Small-Band-Gap Photoconducting
Material

Dehnen, Stefanie

K₂Hg₂Te₃: Straightforward and Large-Scale Mercury-Flux Synthesis of a Small-Band-Gap Photoconducting Material

Version 2 2019-03-25, 19:00

Version 1 2018-09-25, 11:41

Posted on 2019-03-25 - 19:00

K₂Hg₂Te₃ was synthesized via a mercury-flux synthesis pathway. Single-crystal and powder X-ray diffraction reveal the compound to be isostructural to its lighter congener K₂Hg₂Se₃, yet exhibiting enhanced photoconductivity and electrical conductivity of (several) orders of magnitude and a decreased thermal conductivity and band gap. In this report, we elaborate on the synthesis and properties of the novel ternary compound.

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Thiele, Günther; Bron, Philipp; Lippert, Sina; Nietschke, Frederik; Oeckler, Oliver; Koch, Martin; et al. (2018). K₂Hg₂Te₃: Straightforward and Large-Scale Mercury-Flux Synthesis of a Small-Band-Gap Photoconducting Material. ACS Publications. Collection. https://doi.org/10.1021/acs.inorgchem.8b02310

https://doi.org/10.1021/acs.inorgchem.8b02310

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