K10M4Sn4S17 (M = Mn, Fe, Co, Zn): Soluble Quaternary Sulfides with
the Discrete [M4Sn4S17]10- Supertetrahedral Clusters
Posted on 2003-07-19 - 00:00
Four cubic compounds are reported that contain the supertetrahedral cluster [M4Sn4S17]10- where M = Mn, Fe, Co, Zn. The
cluster features a central quadruply bridging sulfide ion (μ4-S) that
holds together four divalent M atoms in a tetrahedral arrangement.
This core is capped with four tridentate [SnS4]4- fragments to
complete the structure.
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Palchik, Oleg; Iyer, Ratnasabapathy G.; Liao, J. H.; Kanatzidis, Mercouri G. (2016). K10M4Sn4S17 (M = Mn, Fe, Co, Zn): Soluble Quaternary Sulfides with
the Discrete [M4Sn4S17]10- Supertetrahedral Clusters. ACS Publications. Collection. https://doi.org/10.1021/ic034600l
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AUTHORS (4)
- OPOleg PalchikRIRatnasabapathy G. IyerJLJ. H. LiaoMKMercouri G. Kanatzidis
