Interplay between Dopant Species and a Spin-Crossover
Host Lattice during Light-Induced Excited-Spin-State Trapping Probed
by Electron Paramagnetic Resonance Spectroscopy

Fedin, Matvey V.

Interplay between Dopant Species and a Spin-Crossover Host Lattice during Light-Induced Excited-Spin-State Trapping Probed by Electron Paramagnetic Resonance Spectroscopy

Version 2 2018-07-11, 18:55

Version 1 2018-07-11, 18:52

Posted on 2018-07-11 - 18:55

Q-band electron paramagnetic resonance (EPR) data conclusively demonstrate that the iron and cobalt centers in the solid solution [Fe(bpp)₂]_0.97[Co(terpy)₂]_0.03[BF₄]₂ (bpp = 2,6-dipyrazol-1-ylpyridine) undergo allosteric spin-state switching during light-induced excited-spin-state trapping (LIESST) at 20 K and thermal relaxation around 80 K. EPR of [Cu(terpy)₂]²⁺ and [Cu(bpp)₂]²⁺, doped into the same host lattice, also indicates expansion of the copper coordination sphere during LIESST excitation.

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Tumanov, Sergey V.; Veber, Sergey L.; Greatorex, Sam; Halcrow, Malcolm A.; Fedin, Matvey V. (2018). Interplay between Dopant Species and a Spin-Crossover Host Lattice during Light-Induced Excited-Spin-State Trapping Probed by Electron Paramagnetic Resonance Spectroscopy. ACS Publications. Collection. https://doi.org/10.1021/acs.inorgchem.8b01096

https://doi.org/10.1021/acs.inorgchem.8b01096

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