Influence of Sodium Chloride on the Formation and
Dissociation Behavior of CO2 Gas Hydrates
Version 2 2017-09-21, 04:29
Version 1 2017-08-25, 16:34
Posted on 2017-09-21 - 04:29
We
present an experimental study on the formation and dissociation
characteristics of carbon dioxide (CO2) gas hydrates using
Raman spectroscopy. The CO2 hydrates were formed from sodium
chloride/water solutions with salinities of 0–10 wt %, which
were pressurized with liquid CO2 in a stirred vessel at
6 MPa and a subcooling of 9.5 K. The formation of the CO2 hydrate resulted in a hydrate gel where the solid hydrate can be
considered as the continuous phase that includes small amounts of
a dispersed liquid water-rich phase that has not been converted to
hydrate. During the hydrate formation process we quantified the fraction
of solid hydrate, xH, and the fraction
of the dispersed liquid water-rich phase, xL, from the signature of the hydroxyl (OH)-stretching vibration of
the hydrate gel. We found that the fraction of hydrate xH contained in the hydrate gel linearly depends on the
salinity of the initial liquid water-rich phase. In addition, the
ratio of CO2 and water was analyzed in the liquid water-rich
phase before hydrate formation, in the hydrate gel during growth and
dissociation, and after its complete dissociation again in the liquid
water-rich phase. We observed a supersaturation of CO2 in
the water-rich phase after complete dissociation of the hydrate gel
and were able to show that the excess CO2 exists as dispersed
micro- or nanoscale liquid droplets in the liquid water-rich phase.
These residual nano- and microdroplets could be a possible explanation
for the so-called memory effect.
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Holzammer, Christine; Schicks, Judith M.; Will, Stefan; Braeuer, Andreas S. (2017). Influence of Sodium Chloride on the Formation and
Dissociation Behavior of CO2 Gas Hydrates. ACS Publications. Collection. https://doi.org/10.1021/acs.jpcb.7b05411
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AUTHORS (4)
CH
Christine Holzammer
JS
Judith M. Schicks
SW
Stefan Will
AB
Andreas S. Braeuer