In Situ Time-Resolved Observation of the Development
of Intracrystalline Mesoporosity in USY Zeolite
Version 3 2016-12-09, 20:20
Version 2 2016-12-05, 17:34
Version 1 2016-12-02, 16:49
Posted on 2016-12-02 - 00:00
The development of intracrystalline
mesoporosity within zeolites
has been a long-standing goal in catalysis as it greatly contributes
to alleviating the diffusion limitations of these widely used microporous
materials. The combination of in situ synchrotron X-ray diffraction
and liquid-cell transmission electron microscopy enabled the first
in situ observation of the development of intracrystalline mesoporosity
in zeolites and provided structural and kinetic information on the
changes produced in zeolites to accommodate the mesoporosity. The
interpretation of the time-resolved diffractograms together with computational
simulations evidenced the formation of short-range hexagonally ordered
mesoporosity within the zeolite framework, and the in situ electron
microscopy studies allowed the direct observation of structural changes
in the zeolite during the process. The evidence for the templating
and protective role of the surfactant and the rearrangement of the
zeolite crystal to accommodate intracrystalline mesoporosity opens
new and exciting opportunities for the production of tailored hierarchical
zeolites.
CITE THIS COLLECTION
DataCite
3 Biotech
3D Printing in Medicine
3D Research
3D-Printed Materials and Systems
4OR
AAPG Bulletin
AAPS Open
AAPS PharmSciTech
Abhandlungen aus dem Mathematischen Seminar der Universität Hamburg
ABI Technik (German)
Academic Medicine
Academic Pediatrics
Academic Psychiatry
Academic Questions
Academy of Management Discoveries
Academy of Management Journal
Academy of Management Learning and Education
Academy of Management Perspectives
Academy of Management Proceedings
Academy of Management Review
Linares, Noemi; Sachse, Alexander; Serrano, Elena; Grau-Atienza, Aida; De Oliveira Jardim, Erika; Silvestre-Albero, Joaquín; et al. (2016). In Situ Time-Resolved Observation of the Development
of Intracrystalline Mesoporosity in USY Zeolite. ACS Publications. Collection. https://doi.org/10.1021/acs.chemmater.6b03688
or
Select your citation style and then place your mouse over the citation text to select it.
SHARE
Usage metrics
Read the peer-reviewed publication
AUTHORS (11)
NL
Noemi Linares
AS
Alexander Sachse
ES
Elena Serrano
AG
Aida Grau-Atienza
ED
Erika De Oliveira Jardim
JS
Joaquín Silvestre-Albero
MC
Marco Aurelio Liutheviciene Cordeiro
FF
François Fauth
GB
Garikoitz Beobide
OC
Oscar Castillo
JG
Javier García-Martínez