Green Synthesis
of α‑Keton Thiol Ester
via Photocatalytic Oxidative Radical Addition of Thioic Acid to Alkene
Posted on 2023-05-30 - 13:05
α-Keton sulfides are versatile building blocks
in organic
synthesis. From thioic acids and alkenes, we were able to develop
the direct synthesis of α-keton thiol esters via photocatalytic
oxidative radical additions. This reaction well matches the idea of
green chemistry. It takes the advantage of thioxanthone as an inexpensive
organic photocatalyst, O2 as a green oxidant, EtOAc as
a green solvent, and visible light as a sustainable energy source,
and the only byproduct is water.
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Zhou, Xiyan; Li, Ruining; Sun, Zhankui (2023). Green Synthesis
of α‑Keton Thiol Ester
via Photocatalytic Oxidative Radical Addition of Thioic Acid to Alkene. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.3c01481
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