Gadolinium Oxalate Derivatives with Enhanced Magnetocaloric
Effect via Ionothermal Synthesis

Tong, Ming-Liang

Gadolinium Oxalate Derivatives with Enhanced Magnetocaloric Effect via Ionothermal Synthesis

Posted on 2014-09-02 - 00:00

Two new oxalate-bridged Gd(III) coordination polymers, namely, (choline)[Gd(C₂O₄)(H₂O)₃Cl]Cl·H₂O (1) and [Gd(C₂O₄)(H₂O)₃Cl] (2), were first obtained ionothermally by using a deep eutectic solvent (DES). The magnetic studies and heat capacity measurements reveal that the two-dimensional Gd(III)-based coordination polymer of 2 has the higher magnetic density and exhibits a larger cryogenic magnetocaloric effect (MCE) (ΔS_m = 48 J kg^–1 K^–1 for ΔH = 7 T at 2.2 K).

CITE THIS COLLECTION

Meng, Yan; Chen, Yan-Cong; Zhang, Ze-Min; Lin, Zhuo-Jia; Tong, Ming-Liang (2016). Gadolinium Oxalate Derivatives with Enhanced Magnetocaloric Effect via Ionothermal Synthesis. ACS Publications. Collection. https://doi.org/10.1021/ic501013x

https://doi.org/10.1021/ic501013x

or

Select your citation style and then place your mouse over the citation text to select it.