Formation of Nanoparticles by Intramolecular Cross-Linking: Following the
Reaction Progress of Single Polymer Chains by Atomic Force Microscopy
Posted on 2007-09-19 - 00:00
Aliphatic polycarbonates with pendant vinyl groups were transformed into nanoparticles through intramolecular olefin cross-metathesis under dilute conditions. Reaction progress was monitored by AFM, revealing a range of structures from extended linear molecules at 0% cross-linking to isolated particles at 76% cross-linking.
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Cherian, Anna E.; Sun, Frank C.; Sheiko, Sergei S.; Coates, Geoffrey W. (2016). Formation of Nanoparticles by Intramolecular Cross-Linking: Following the
Reaction Progress of Single Polymer Chains by Atomic Force Microscopy. ACS Publications. Collection. https://doi.org/10.1021/ja074301l