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Formation of Nanoparticles by Intramolecular Cross-Linking:  Following the Reaction Progress of Single Polymer Chains by Atomic Force Microscopy

Posted on 2007-09-19 - 00:00
Aliphatic polycarbonates with pendant vinyl groups were transformed into nanoparticles through intramolecular olefin cross-metathesis under dilute conditions. Reaction progress was monitored by AFM, revealing a range of structures from extended linear molecules at 0% cross-linking to isolated particles at 76% cross-linking.

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