Formation of Cross-Linked Films from Immiscible Precursors
through Sintering of Vitrimer Nanoparticles

Montarnal, Damien

Formation of Cross-Linked Films from Immiscible Precursors through Sintering of Vitrimer Nanoparticles

Posted on 2018-03-08 - 19:37

Colloidal dispersions of epoxy-acid vitrimers have been synthesized by miniemulsion polymerization. This versatile strategy enables obtaining stable cross-linked particles, even from initially incompatible precursors, while minimizing hydrolysis of the ester bonds formed during the curing. After drying of the latexes, trans-esterification exchanges occurring at high temperatures through interparticle interfaces induces an efficient sintering into homogeneous cross-linked polymer films.

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Tran, Thi Nga; Rawstron, Eleanor; Bourgeat-Lami, Elodie; Montarnal, Damien (2018). Formation of Cross-Linked Films from Immiscible Precursors through Sintering of Vitrimer Nanoparticles. ACS Publications. Collection. https://doi.org/10.1021/acsmacrolett.8b00173

https://doi.org/10.1021/acsmacrolett.8b00173

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