Extension to the Silyl-Tethered Radical Cyclization:
Cyclohex-2-en-1-oxy Vinyl Silanes in Stereoselective Radical Addition/Cyclization
Cascades
Posted on 2017-03-30 - 16:19
A novel
radical cascade reaction of xanthates with 1-[(vinyldimethylsilyl)oxy]cyclohex-2-enes
is developed. Due to the steric and electronic differentiation of
the two olefinic functions, exclusive regioselectivity and high stereoselectivity
of the addition–cyclization are observed. Several methods for
modification of both the silicon tether and the xanthate function
are reported.
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Mikhaylov, Andrey
A.; Zard, Samir Z. (2017). Extension to the Silyl-Tethered Radical Cyclization:
Cyclohex-2-en-1-oxy Vinyl Silanes in Stereoselective Radical Addition/Cyclization
Cascades. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b00627
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