Exploring the Reducing Ability of Organic Dye (Acr+‑Mes) for Fluorination and Oxidation of Benzylic C(sp3)–H Bonds under Visible Light Irradiation
Posted on 2017-05-22 - 19:15
The excellent oxidizing
capability of acridinium-based organic
dye (Acr+-Mes) is fully studied in photoredox catalysis.
However, its reducing ability is always considered weak for organic
transformation. The reducing ability of Acr+-Mes is developed
by Selectfluor to achieve effective fluorination and oxidation of
benzylic C(sp3)–H bonds under visible light irradiation,
which is not available for the direct use of oxidizing ability of
excited Acr+-Mes. Mechanistic insights provided strong
evidence for the oxidative quenching of Acr+-Mes.
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Xiang, Ming; Xin, Zhi-Kun; Chen, Bin; Tung, Chen-Ho; Wu, Li-Zhu (2017). Exploring the Reducing Ability of Organic Dye (Acr+‑Mes) for Fluorination and Oxidation of Benzylic C(sp3)–H Bonds under Visible Light Irradiation. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b01270
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