Equation of State and Amorphization of Ca<sub>9</sub>R(VO<sub>4</sub>)<sub>7</sub> (R = La, Nd, Gd): A Combined High-Pressure X‑ray Diffraction and Raman Spectroscopy Study

Published on 2018-10-11T14:06:39Z (GMT) by
Ca<sub>9</sub>R­(VO<sub>4</sub>)<sub>7</sub> (R = rare earth) multicomponent oxides of a whitlockite-related structure are under consideration for applications in optoelectronics. In this work, the Czochralski-grown Ca<sub>9</sub>R­(VO<sub>4</sub>)<sub>7</sub> crystals were investigated as a function of pressure by powder X-ray diffraction and single-crystal Raman spectroscopy. The diffraction experiments were performed at the ALBA synchrotron under pressures ranging up to 9.22(5), 10.7(1), and 8.55(5) GPa for R = La, Nd, and Gd, respectively, to determine the third order equation of state (EOS) parameters. Fitting of the Birch–Murnaghan EOS provided the isothermal bulk moduli <i>K</i><sub>0</sub> = 63(4), 63(2), and 61(5) GPa for these three orthovanadates. These values are apparently lower than that reported for structurally related tricalcium vanadate Ca<sub>3</sub>(VO<sub>4</sub>)<sub>2</sub>. The compressibility anisotropy was observed; the lattice is markedly stiffer in [001] than in [100] direction. For Ca<sub>9</sub>Nd­(VO<sub>4</sub>)<sub>7</sub>, the variation of the diffractograms just above 10 GPa provides an indication on the beginning of amorphization process; during pressure release the whitlockite-like structure is recovered. Raman spectroscopy measurements for single crystals of the above-mentioned rare-earth vanadates and Ca<sub>9</sub>Y­(VO<sub>4</sub>)<sub>7</sub> were performed (the maximum pressures achieved were 16.3(1), 21.2(1), 15.3(1), and 18.6(1) GPa for R = Y, La, Nd, and Gd, respectively). These measurements reveal a partially reversible phase transition interpreted as amorphization, with an onset at the pressure of ∼9–10 GPa, characterized by broadening of the peaks and their shift to lower energies.

Cite this collection

Kosyl, Katarzyna M.; Paszkowicz, Wojciech; Ermakova, Olga; Wlodarczyk, Damian; Suchocki, Andrzej; Minikayev, Roman; et al. (2018): Equation of State and Amorphization of Ca9R(VO4)7 (R = La, Nd, Gd): A Combined High-Pressure

X‑ray Diffraction and Raman Spectroscopy Study. ACS Publications. Collection.