Enhancement of Upconversion Luminescence by the Construction of a 3Yb-Er-Hf Sublattice Energy Cluster and Surface Defect Elimination

Nanotetragonal LiYF₄:RE (Tm,Er,Ho) is a kind of excellent upconversion luminescence (UCL) material potentially used in many fields, while the enhancement of UC emission and regulation of luminescence lifetime are still a challenge. Herein, a strategy was reported to enhance UCL performance with the aid of the construction of a 3Yb-Er-Hf sublattice energy cluster with the introduction of Hf⁴⁺ and the interception of surface defect fluorescence quenching. UCL was obviously decreased by Hf⁴⁺ doping without surface defect elimination, but after the interception of surface defect quenching, UCL was dramatically enhanced more than 300-fold with an Er³⁺/Hf⁴⁺ mole ratio of 1:1. The contribution of UCL enhancement by the construction of a 3Yb-Er-Hf sublattice energy cluster is about 1.5 times of the sample without energy cluster construction. Interestingly, the lifetime of UCL can also be regulated by this strategy. According to the results of systematical microstructure analyses and UCL performance behaviors examined by X-ray powder diffraction (XRD), small-angle X-ray scattering (SAXS), transmission electron microscopy (TEM), nuclear magnetic resonance (NMR), and fluorescence spectrophotometry (FS) methods, the possible mechanism of UCL enhancement was proposed. This work may be an inspiration for researchers to design and develop high-performance UCL nanomaterials.